85433-88-1

Basic information

• Product Name: 1-methoxy-4-(3-methylpent-1-yn-1-yl)benzene
• Synonyms: 1-methoxy-4-(3-methylpent-1-yn-1-yl)benzene
• CAS NO: 85433-88-1
• Molecular Weight: 188.269
• Mol File: 85433-88-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-methoxy-4-(3-methylpent-1-yn-1-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methoxy-4-(3-methylpent-1-yn-1-yl)benzene(85433-88-1)
• EPA Substance Registry System: 1-methoxy-4-(3-methylpent-1-yn-1-yl)benzene(85433-88-1)

Safety Data

• Hazardous Substances Data: 85433-88-1(Hazardous Substances Data)

Upstream product

• 60059-95-2 C₉H₇ClF₂O 
• 598-30-1 sec.-butyllithium 
• 75505-87-2 1-(sec-butyl)-2,4,6-triphenylpyridin-1-ium tetrafluoroborate 
• 513-48-4 2-butyl iodide 
• 768-60-5 4-methoxyphenylacetylen 
• 14774-77-7 p-methoxyphenyllithium 

Relevant articles and documents

Redox-Activated Amines in C(sp3)-C(sp) and C(sp3)-C(sp2) Bond Formation Enabled by Metal-Free Photoredox Catalysis

The amino group represents one of the most prevalent structural motifs in organic chemistry. Therefore, application of amines as alkylating agents in synthesis is highly compelling. Herein, we present a metal-free photoredox strategy for the formation of C(sp3)-C(sp) and C(sp3)-C(sp2) bonds from redox-activated primary amine derivatives. The developed reaction of 2,4,6-triphenylpyridinium salts with alkynyl p-tolylsulfones, leading to functionalized alkynes, is easily scalable and offers broad substrate scope, high chemoselectivity, and mild conditions. Its potential is also highlighted by diversification of complex molecular scaffolds. Additionally, the approach is also suitable for synthesis of (E)-alkenes from vinyl phenyl sulfones. Mechanistic studies contribute to the elucidation of unexpected differences in reactivity of primary and secondary alkyl substituted pyridinium salts.

REACTION DE PERHALOSTYRENES AVEC LES ORGANOLITHIENS. PREPARATION D'ARYL-1 ALCYNES-1 RAMIFIES PAR L'INTERMEDIAIRE D'ARYL FLUORO ACETYLENES

Organolithium compounds react with 1-aryl 2-chloro 1,2-difluoroethylene to give derivatives of type Ar-C*C-R'.Hydrolysis of the intermediate carbanionic species yilds the corresponding α,β-difluorostyrenes.