855194-85-3

Basic information

• Product Name: (2,4-dichlorophenyl)(4-nitrophenyl)methanone
• Synonyms: (2,4-dichlorophenyl)(4-nitrophenyl)methanone
• CAS NO: 855194-85-3
• Molecular Weight: 296.109
• Mol File: 855194-85-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (2,4-dichlorophenyl)(4-nitrophenyl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: (2,4-dichlorophenyl)(4-nitrophenyl)methanone(855194-85-3)
• EPA Substance Registry System: (2,4-dichlorophenyl)(4-nitrophenyl)methanone(855194-85-3)

Safety Data

• Hazardous Substances Data: 855194-85-3(Hazardous Substances Data)

Upstream product

• 122-04-3 4-nitro-benzoyl chloride 
• 541-73-1 1,3-Dichlorobenzene 
• 68716-47-2 2,4-dichlorophenylboronic acid 
• 41022-54-2 ethyl 2-(2, 4-dichlorophenyl)acetate 
• 98-95-3 nitrobenzene 

Downstream Products

• 1321599-97-6 2,4-dichloro-4'-nitrobenzophenone hydrazone 
• 858475-03-3 [6]quinolyl-(2,4-dichloro-phenyl)-methanol 
• 855614-29-8 (2,4-dichloro-phenyl)-(1,2,3,4-tetrahydro-[6]quinolyl)-ketone 
• 855614-37-8 [6]quinolyl-(2,4-dichloro-phenyl)-ketone 
• 50275-11-1 4'-amino-2,4-dichloro-benzophenone 

Relevant articles and documents

Synthesis, structure, and characterization of picolyl- and benzyl-linked biphenyl palladium N-heterocyclic carbene complexes and their catalytic activity in acylative cross-coupling reactions

N-heterocyclic carbene ligands with picolyl (L1H2Br2, L3H2Br2) and benzyl (L2H2Br2, L4H2Br2) linked biphenyl backbone were synthesized and characterized. Their palladium(II) complexes [PdL1]Br2 (1), [PdL2Br2] (2), [PdL3]Br2 (3), and [PdL4Br2] (4) were synthesized by direct method using Pd(OAc)2. All complexes (1–4) were characterized by CHN analysis, electrospray ionization-MS, nuclear magnetic resonance, and single-crystal X-ray diffraction. Molecular structures confirm the distorted square planar geometry around the Pd(II) center. All of them showed good catalytic activity in acylative Suzuki cross coupling of phenyl boronic acid with benzoyl chloride to afford benzophenone in good yields.

Method for acylation or sulphonylation of an aromatic compound

The present invention relates to a process for the acylation or sulphonylation of an aromatic compound. More particularly, the invention relates to a process for the acylation or sulphonylation of an activated or deactivated aromatic compound. The invention is applied to the preparation of aromatic ketones or sulphones. The process for the acylation or sulphonylation of an aromatic compound which consists in reacting at least one aromatic compound with an acylating or sulphonylating agent, in the presence of a Friedel-Crafts catalyst is characterized in that the acylation or sulphonylation reaction is carried out in liquid phase under microwave irradiation.