85630-18-8

Basic information

• Product Name: 4-methoxyphenyl diethylcarbamate
• CAS NO: 85630-18-8
• Molecular Formula: C₁₂H₁₇NO₃
• Molecular Weight: 223.2683
• Mol File: 85630-18-8.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 316.5°C at 760 mmHg
• Flash Point: 145.2°C
• Density: 1.074g/cm³
• Vapor Pressure: 0.000409mmHg at 25°C
• Refractive Index: 1.507
• CAS DataBase Reference: 4-methoxyphenyl diethylcarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methoxyphenyl diethylcarbamate(85630-18-8)
• EPA Substance Registry System: 4-methoxyphenyl diethylcarbamate(85630-18-8)

Safety Data

• Hazardous Substances Data: 85630-18-8(Hazardous Substances Data)

Upstream product

• 88-10-8 N,N-diethylcarbamyl chloride 
• 150-76-5 4-methoxy-phenol 
• 124-38-9 carbon dioxide 
• 5720-07-0 4-methoxyphenylboronic acid 
• 109-89-7 diethylamine 

Downstream Products

• 85650-28-8 O-(2-carboxy-4-methoxy)phenyl N,N-diethylcarbamate 
• 85630-26-8 O-(2-methyl-4-methoxy)phenyl N,N-diethylcarbamate 
• 127136-76-9 C₁₂H₂₁N₂O₃P 
• 251564-24-6 N,N-diethyl-2,5-dimethoxy-3-(diethylcarbamoyl)benzamide 
• 312534-71-7 2-iodo-4-methoxyl-phenol 
• 333385-17-4 (-)-7-(2-hydroxy-5-methoxy-phenyl)-5-methyl-hept-6-ynoic acid methyl ester 
• 613-37-6 4-methoxylbiphenyl 
• 1245824-47-8 4-methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl N,N-diethylcarbamate 
• 27347-14-4 N-(4-methoxyphenyl)morpholine 
• 705-15-7 1-(2-hydroxy-5-methoxyphenyl)ethan-1-one 
• 4998-49-6 (4-chlorophenyl)(2-hydroxy-5-methoxyphenyl)methanone 
• 7182-32-3 2-phenyl-5-methoxybenzo[b]furan 
• 35715-67-4 1-(4-methoxyphenyl)-1H-pyrazole 
• 5145-71-1 1-(p-methoxyphenyl)pyrrole 

Relevant articles and documents

C-O Bond Silylation Catalyzed by Iron: A General Method for the Construction of Csp2-Si Bonds

The iron-catalyzed construction of Csp2-Si bonds via unreactive C-O bonds possesses a challenging topic in organic chemistry. Herein we report an iron-catalyzed silylation of aryl and alkenyl carbamates via C-O bond activation. This protocol fe

N -Arylation of (hetero)arylamines using aryl sulfamates and carbamates via C-O bond activation enabled by a reusable and durable nickel(0) catalyst

An effective and general aryl amination protocol has been developed using a magnetically recoverable Ni(0) based nanocatalyst. This new stable catalyst was prepared on Fe3O4@SiO2 modified by EDTA and investigated by FT-IR, EDX, TEM, XRD, DLS, FE-SEM, XPS, NMR, TGA, VSM, ICP and elemental analysis techniques. The reaction proceeded via carbon-oxygen bond cleavage of (hetero)aryl carbamates and sulfamates under simple and mild conditions without the use of any external ligands. This method demonstrated functional group tolerance in the N-arylation of various nitrogen-containing compounds as well as aliphatic amines, anilines, pyrroles, pyrazoles, imidazoles, indoles, and indazoles with good to excellent yields. Furthermore, the catalyst could be easily recovered by using an external magnetic field and directly reused at least six times without notable reduction in its activity. This journal is

Directed ortho-Metalation of Aryl Amides, O-Carbamates, and Methoxymethoxy Systems: Directed Metalation Group Competition and Cooperation

A systematic study on the competitive metalation of derivatives containing four directed metalation groups (DMGs), namely, Cl, OMe, methoxymethoxy (OMOM), and CONEt2, in comparison with the OCONEt2 DMG is described. In addition, the