857684-82-3

Basic information

• Product Name: diallylethylphosphine
• Synonyms: diallylethylphosphine
• CAS NO: 857684-82-3
• Molecular Weight: 142.181
• Mol File: 857684-82-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: diallylethylphosphine(CAS DataBase Reference)
• NIST Chemistry Reference: diallylethylphosphine(857684-82-3)
• EPA Substance Registry System: diallylethylphosphine(857684-82-3)

Safety Data

• Hazardous Substances Data: 857684-82-3(Hazardous Substances Data)

Upstream product

• 925-90-6 ethylmagnesium bromide 
• 119841-34-8 cis-2,10-dimethyl-<1,2,3>benzothiadiphospholo<2,3-b><1,2,3>benzothiadiphosphole 
• 1730-25-2 allylmagnesium bromide 

Relevant articles and documents

Highly atom-economic one-pot formation of three different C-P bonds: General synthesis of acyclic tertiary phosphine sulfides

The reaction of benzothiadiphosphole 1 with an equimolar mixture of R 1MgBr and R2MgBr gave intermediate A′, which, after only 4-5 min, was treated with an equimolar amount of R3MgBr, giving the asymmetric phosphine PR1R2R3 in 45% overall yield (75-80% yield when R1 = R2 and 85-90% yield when R1 = R2 = R3) and the byproduct 6 in 90% yield. The treatment of 6 with PCl3 quantitatively regenerates the starting reagent 1. Treatment of the phosphines with elemental sulfur gave the corresponding sulfides.