861-67-6Relevant articles and documents
Visible-light-mediated, nitrogen-centered radical amination of tertiary alkyl halides under metal-free conditions to form α-tertiary amines
Brueckner, Alexander C.,Hancock, Erin N.,Anders, Evan J.,Tierney, Matthew M.,Morgan, Heather R.,Scott, Kristina A.,Lamar, Angus A.
supporting information, p. 4387 - 4392 (2016/06/06)
A mild and operationally convenient amino-functionalization of a range of tertiary alkyl halides by reaction with iminoiodinanes (PhINNs) and I2 has been developed. According to the mechanistic experiments described within, the reaction is spec
Iron-catalyzed efficient intermolecular amination of C(sp3)-H bonds with bromamine-T as nitrene source
Wang, Haiyu,Li, Yuxi,Wang, Zhiming,Lou, Jun,Xiao, Yuling,Qiu, Guofu,Hu, Xianming,Altenbach, Hans-Josef,Liu, Peng
, p. 25287 - 25290 (2014/07/07)
[Fe(N4Py)(CH3CN)](ClO4)2 can efficiently catalyze intermolecular nitrene insertion of sp3 C-H bonds with bromamine-T as the nitrene source, forming the desired tosylprotected amines with NaBr as the by-product.
Hydrous zinc halide-catalyzed aminosulfonation of hydrocarbons
Kalita, Biswajit,Lamar, Angus A.,Nicholas, Kenneth M.
supporting information; experimental part, p. 4291 - 4293 (2009/03/12)
Benzylic and allylic hydrocarbons are selectively converted to the corresponding sulfonamides by a ZnBr2-H2O-catalyzed reaction with PhI=NTs; saturated adamantane is aminosulfonated at the tertiary C-H bond. The Royal Society of Chemistry.