865760-13-0Relevant articles and documents
Palladium-catalyzed acetylation of arylbromides
Ariki, Zach,Garg, Neil K.,Kaiser, Daniel,Kelleghan, Andrew V.,Mehta, Milauni M.
, p. 68 - 83 (2021/04/14)
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Base-Mediated Meerwein-Ponndorf-Verley Reduction of Aromatic and Heterocyclic Ketones
Boit, Timothy B.,Mehta, Milauni M.,Garg, Neil K.
supporting information, p. 6447 - 6451 (2019/08/20)
An experimental protocol to achieve the Meerwein-Ponndorf-Verley (MPV) reduction of ketones under mildly basic conditions is reported. The transformation is tolerant of a range of ketone substrates, including O- and S-containing heterocycles, is scalable, and shows potential to be used as a platform to access enantioenriched products. These studies provide a general method for achieving the reduction of ketones under mildly basic conditions and offer an alternative protocol to more well-known Al-based MPV reduction conditions.
A new synthesis of benzofurans from phenols via claisen rearrangement and ring-closing metathesis
Tsai, Tzu-Wei,Wang, Eng-Chi,Li, Sie-Rong,Chen, Yung-Hua,Lin, Yu-Li,Wang, You-Feng,Huang, Keng-Shiang
, p. 1307 - 1318 (2007/10/03)
Based on Claisen rearrangement, the double bond isomerization of O-allyl function together with the formation of O-vinyl function in one pot, and ring-closing metathesis (RCM), various phenols were transformed into various benzofurans in good yields.
