87223-52-7

Basic information

• Product Name: C₁₄H₁₈N₄O₅
• CAS NO: 87223-52-7
• Molecular Weight: 322.321
• Mol File: 87223-52-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₄H₁₈N₄O₅(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₁₈N₄O₅(87223-52-7)
• EPA Substance Registry System: C₁₄H₁₈N₄O₅(87223-52-7)

Safety Data

• Hazardous Substances Data: 87223-52-7(Hazardous Substances Data)

Upstream product

• 2719-15-5 2-methyl-4-nitroacetanilide 
• 34840-23-8 1,3-Dicarbomethoxy-S-methylisothiourea 
• 56891-59-9 N-(4-Amino-2-methyl-phenyl)-acetamide 

Relevant articles and documents

Quinone Imine Route to Benzimidazol-2-ylcarbamates. Part 1. Synthesis of Open-chain and Cyclic 5-Acylamino Derivatives.

The synthesis of the N',N''-bismethoxycarbonyl-N-(4-acylaminophenyl)guanidines (4) and (7) is described.Oxidation of these with LTA has led to the benzimidazol-2-ylcarbamates. (8), (9) and (10) through a regiospecific cyclisation of quinone imine intermediates.If the acylamino group is part of a ring, the yield of benzimidazoles (15) increases with the size of the lactam ring.The direction of ring closure may be controlled by electronic and steric factors.