875433-40-2Relevant articles and documents
Lipase-catalyzed asymmetric dealkoxylcarbonylation of σ-symmetrical β-ketodiesters and its application to the synthesis of (-)-podocarpic acid
Katoh, Takahiro,Awasaguchi, Ken-Ichiro,Mori, Daisuke,Kimura, Hiroyuki,Kajimoto, Tetsuya,Node, Manabu
, p. 2919 - 2922 (2007/10/03)
Optically active 2,6-dimethylcyclohexanone-2-carboxylate was prepared by PLE-catalyzed dealkoxycarbonylation of σ-symmetrical β-ketodiesters, which possess quarternary carbons at α- and α′-positions. Moreover, (-)-podocarpic acid was prepared in a short s