87639-09-6

Basic information

• Product Name: Benzenemethanol, 4-fluoro-a-(2-phenylethenyl)-, acetate
• CAS NO: 87639-09-6
• Molecular Formula: C17H15FO2
• Molecular Weight: 270.303
• Mol File: 87639-09-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 4-fluoro-a-(2-phenylethenyl)-, acetate(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 4-fluoro-a-(2-phenylethenyl)-, acetate(87639-09-6)
• EPA Substance Registry System: Benzenemethanol, 4-fluoro-a-(2-phenylethenyl)-, acetate(87639-09-6)

Safety Data

• Hazardous Substances Data: 87639-09-6(Hazardous Substances Data)

Upstream product

• 459-57-4 4-fluorobenzaldehyde 
• 108-24-7 acetic anhydride 
• 134747-51-6 trans-1-(4-fluorophenyl)-3-phenylprop-2-en-1-ol 

Downstream Products

• 87639-10-9 1-Fluoro-4-[1-((E)-styryl)-but-3-ynyl]-benzene 

Relevant articles and documents

Organotin Nucleophiles. 5. Palladium-Catalyzed Allylic Propargylation with Allenylstannane

Allenyltrialkylstannanes were found to react with various allylic acetates in the presence of catalytic amounts of Pd(PPh3)4 under mild neutral conditions, providing a novel approach for obtaining the 1,5-enyne carbon skeleton.The regioselectivity of propargylation depends largely on the electron-withdrawing properties of the substituents at the two ends of the allylic system: substitution occurs at the end of closer proximity to the more electronegative group.Allylic cyanohydrin acetates are substituted at a position α to the cyano group along with formation of a reduced side product.Several mechanistic aspects of these reactions are discussed.