877667-26-0

Basic information

• Product Name: 9H-Fluorene-2-carboxylic acid, 9-oxo-, 3-[3-(trifluoromethyl)-3H-diazirin-3-yl]phenyl ester
• CAS NO: 877667-26-0
• Molecular Formula: C22H11F3N2O3
• Molecular Weight: 408.336
• Mol File: 877667-26-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 9H-Fluorene-2-carboxylic acid, 9-oxo-, 3-[3-(trifluoromethyl)-3H-diazirin-3-yl]phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 9H-Fluorene-2-carboxylic acid, 9-oxo-, 3-[3-(trifluoromethyl)-3H-diazirin-3-yl]phenyl ester(877667-26-0)
• EPA Substance Registry System: 9H-Fluorene-2-carboxylic acid, 9-oxo-, 3-[3-(trifluoromethyl)-3H-diazirin-3-yl]phenyl ester(877667-26-0)

Safety Data

• Hazardous Substances Data: 877667-26-0(Hazardous Substances Data)

Upstream product

• 154187-45-8 3-(3-Methoxyphenyl)-3-(trifluoromethyl)diaziridine 
• 205485-24-1 3-(3-methoxyphenyl)-3-(trifluoromethyl)-3H-diazirine 
• 140854-00-8 2,2,2-Trifluoro-1-(3-methoxyphenyl)ethanone oxime 
• 30724-22-2 2,2,2-trifluoro-1-(3-methoxyphenyl)ethanone 
• 591-20-8 3-Bromophenol 
• 2398-37-0 3-methoxyphenyl bromide 
• 784-50-9 fluorenone-2-carboxylic acid 
• 113787-85-2 3-(3-hydroxyhenyl)-3-(trifluoromethyl)-3H-diazirine 

Relevant articles and documents

Surface modification of nylon 6,6 using a carbene insertion approach

The diazirine functionalised fluorenone, 3-[3-(trifluoromethyl)diazirin-3- yl]phenyl-9-oxo-9H-fluorene-2-carboxylate was synthesised to act as a model compound capable of modifying a wide variety of polymeric substrates. Photochemical activation of the diazirine moiety of the fluorenone derivative was utilised to afford highly reactive carbenes capable of insertion into or addition to a wide variety of functionalities. In this paper the photoinduced attachment of a fluorenone derivative to nylon 6,6 has been studied using UV-visible spectroscopic analysis. Incorporation of the fluorenone chromophore onto the backbone of nylon at different loading levels and after different coating cycles has been investigated and is detailed in this paper. the Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2006.