88039-49-0

Basic information

• Product Name: 2-Propenoic acid, 2-(bromomethyl)-3-phenyl-, ethyl ester, (2Z)-
• CAS NO: 88039-49-0
• Molecular Formula: C12H13BrO2
• Molecular Weight: 269.138
• Mol File: 88039-49-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 2-(bromomethyl)-3-phenyl-, ethyl ester, (2Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 2-(bromomethyl)-3-phenyl-, ethyl ester, (2Z)-(88039-49-0)
• EPA Substance Registry System: 2-Propenoic acid, 2-(bromomethyl)-3-phenyl-, ethyl ester, (2Z)-(88039-49-0)

Safety Data

• Hazardous Substances Data: 88039-49-0(Hazardous Substances Data)

Upstream product

• 140-88-5 ethyl acrylate 
• 100-52-7 benzaldehyde 
• 7042-33-3 ethyl (E)-2-methyl-3-phenyl-2-propenoate 

Downstream Products

• 1190601-44-5 C₁₉H₂₂O₅ 
• 134642-24-3 3-benzylidene-5-(propan-2-yl)tetrahydrofuran-2-one 
• 134642-22-1 cis-3-methylene-4-phenyl-5-(propan-2-yl)tetrahydrofuran-2-one 
• 88039-82-1 2-Acetyl-2-benzyl-4-[1-phenyl-meth-(E)-ylidene]-pentanedioic acid diethyl ester 
• 103548-00-1 cis-4,5-dihydro-5-methyl-3-methylene-4-phenyl-2(3H)-furanone 
• 103548-00-1 trans-4,5-dihydro-5-methyl-3-methylene-4-phenyl-2(3H) furanone 
• 105400-43-9 trans-3-methylene-4,5-diphenyldihydrofuran-2(3H)-one 
• 105400-43-9 (4,5-cis)-3-methylene-4,5-diphenyldihydrofuran-2(3H)-one 
• 88039-66-1 2-Acetyl-4-methylene-3-phenyl-pentanedioic acid diethyl ester 
• 88039-58-1 2-Acetyl-4-[1-phenyl-meth-(E)-ylidene]-pentanedioic acid diethyl ester 
• 135793-87-2 2-(Bromomethyl)-3-phenyl-2-propenoic acid 
• 20593-63-9 2-Benzylacrylic acid ethyl ester 
• 7042-33-3 ethyl (E)-2-methyl-3-phenyl-2-propenoate 
• 134294-40-9 2,5-Bis-[1-phenyl-meth-(E)-ylidene]-hexanedioic acid diethyl ester 

Relevant articles and documents

Hydrodebromination of allylic and benzylic bromides with water catalyzed by a rhodium porphyrin complex

Hydrodebromination of allylic and benzylic bromides was successfully achieved by a rhodium porphyrin complex catalyst using water as the hydrogen source without a sacrificial reductant. Mechanistic investigations suggest that bromine atom abstraction via a rhodium porphyrin metalloradical operates to give the rhodium porphyrin alkyl species and the subsequent hydrolysis of the rhodium porphyrin alkyl species to a hydrocarbon product is a key step to harness the hydrogen from water.

Enzyme-catalyzed synthesis of optically pure β-sulfonamidopropionic acids. Useful starting materials for P-3 site modified renin inhibitors

The novel and efficient of several racemic β-sulfonamidopropionate esters is described. Treatment of the racemic esters with Chymotrypsin or Subtilisin Carlsberg (purified of detergent grade) provided the corresponding (S)-carboxylic acids in 60-90% yield

Necic Acid Synthons. Part 2. Regioselectivity in the Reactions of (Z)-2-Bromomethyl-2-alkenoate Esters with Selected Carbon Nucleophiles

The preparation of selected (Z)-2-bromomethyl-2-alkenoate esters and their subsequent reaction with acetoacetic ester-derived nucleophiles is described.Both the substrate structure and the solvent system have significant effects on the regioselectivity of these nucleophilic displacements.