88088-95-3

Basic information

• Product Name: TRIS-(1-BENZOTRIAZOLYL)METHANE 97
• Synonyms: TRIS-(1-BENZOTRIAZOLYL)METHANE 97;TRIS(1-BENZOTRIAZOLEYL)METHANE;tri(1H-benzo[d][1,2,3]triazol-1-yl)Methane;Tris(1H-benzo[d][1,2,3]triazol-1-yl)Methane;Tris(1H-benzotriazol-1-yl)methane;Tris(1H-benzo[d][1,2,3]triazol-1-yl)
• CAS NO: 88088-95-3
• Molecular Formula: C₁₉H₁₃N₉
• Molecular Weight: 367.37
• Product Categories: C-C Bond Formation;Others;Synthetic Reagents
• Mol File: 88088-95-3.mol
• Article Data: 4

Chemical Properties

• Melting Point: 191-195 °C(lit.)
• Appearance: /
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: TRIS-(1-BENZOTRIAZOLYL)METHANE 97(CAS DataBase Reference)
• NIST Chemistry Reference: TRIS-(1-BENZOTRIAZOLYL)METHANE 97(88088-95-3)
• EPA Substance Registry System: TRIS-(1-BENZOTRIAZOLYL)METHANE 97(88088-95-3)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 88088-95-3(Hazardous Substances Data)

Usage

Description

TRIS-(1-BENZOTRIAZOLYL)METHANE 97 is a novel benzotriazole reagent that possesses unique chemical properties and reactivity. It is a versatile compound with a wide range of applications in various chemical reactions and industries.

Uses

Used in Photodecomposition Reactions:
TRIS-(1-BENZOTRIAZOLYL)METHANE 97 is used as a reactant in photodecomposition reactions, where it aids in the breakdown of complex molecules under the influence of light. Its benzotriazole structure enhances the reactivity and efficiency of these reactions.
Used in Tele Nucleophilic Aromatic Substitutions:
In tele nucleophilic aromatic substitutions, TRIS-(1-BENZOTRIAZOLYL)METHANE 97 serves as a reactant that facilitates the substitution of atoms or groups at a distance from the reaction site. Its unique structure allows for efficient and selective substitution reactions.
Used in Para-Formylation of Nitroarenes via Nucleophilic Substitution:
TRIS-(1-BENZOTRIAZOLYL)METHANE 97 is utilized as a reactant in the para-formylation of nitroarenes through nucleophilic substitution. Its benzotriazole functionality plays a crucial role in the selective formation of para-formyl products, making it a valuable reagent in organic synthesis.

Upstream product

• 95-14-7 1,2,3-Benzotriazole 
• 67-66-3 chloroform 

Downstream Products

• 130749-22-3 C₃₀H₂₉N₉OSi 
• 130749-27-8 Tris-benzotriazol-1-yl-dithioacetic acid benzyl ester 
• 130749-18-7 C₂₆H₁₉N₉ 
• 130749-26-7 2,2,2-Tris-benzotriazol-1-yl-N-benzyl-thioacetamide 
• 130749-21-2 C₂₉H₂₇N₉OSi 
• 174708-74-8 C₂₅H₁₇N₇O₂ 
• 157701-72-9 4-nitro-2-fluorobenzaldehyde 
• 229-87-8 phenanthridine 
• 90-41-5 2-phenylaniline 
• 57507-34-3 3-chloro-4-nitrobenzaldehyde 
• 130759-76-1 C₂₈H₂₁N₉ 
• 130749-20-1 2,2,2-Tris-benzotriazol-1-yl-1-p-tolyl-ethanone 
• 130749-24-5 2,2,2-Tris-benzotriazol-1-yl-N-phenyl-thioacetamide 
• 130749-19-8 2,2,2-Tris-benzotriazol-1-yl-1-phenyl-ethanone 

Relevant articles and documents

Photochemical study of tris(benzotriazol-1-yl)methane

(Chemical Equation Presented) Photodecomposition of tris(benzotrizol-1-yl) methane (1) in benzene gives [1-benzotryazol-1-yl-methylidene]-biphenyl-2- ylamine (2) resulting from the loss of the benzotriazolyl radical and nitrogen followed by addition of benzene. Elimination of the second benzotriazolyl radical from 2 provides the biphenyl-2-ylmethyleneamine radical, which affords phenantridine (3) after ring closure. In contrast, the photolysis of 1 in methanol gives a high yield of benzotriazole (4).

Tris(benzotriazol-1-yl)methane: A -CO2H Synthon for the Preparation of Carboxylic Acids

Lithiation of tris(benzotriazol-1-yl)methane 16 gives the tris(benzotriazolyl)methyl carbanion 17 which affords substitution products 18 with many electrophiles.Acidic hydrolysis of 18 affords the corresponding carboxylic acids 19 in good yield.The syntheses of several α-functionalized carboxylic acids are described.