881397-68-8Relevant articles and documents
d-Fructose Based Spiro-Fused PHOX Ligands: Palladium Complexes and Application in Catalysis
Imrich, Michael R.,Maichle-M?ssmer, C?cilia,Ziegler, Thomas
supporting information, p. 3955 - 3963 (2019/07/03)
Phosphinooxazoline (PHOX) ligands are an important class of ligands in asymmetric catalysis. Recently we reported on the synthesis of d-fructose based spiro-fused PHOX ligands. Here, we now present the application of these ligands in asymmetric alkylation
Use of zinc enolate, free from other metals, in enantioselective palladium-catalyzed allylic alkylation
Kinoshita, Naosumi,Kawabata, Takeo,Tsubaki, Kazunori,Bando, Masahiko,Fuji, Kaoru
, p. 1756 - 1763 (2007/10/03)
Zinc enolate, free from other metal cations directly prepared from malonate and diethylzinc, was proven to be an excellent nucleophile for enantioselective palladium-catalyzed allylic alkylation, particularly for the allylic cation bearing aromatic rings