885056-96-2

Basic information

• Product Name: 5-chloro-2-(pyrrol-1-yl)benzyl alcohol
• Synonyms: 5-chloro-2-(pyrrol-1-yl)benzyl alcohol
• CAS NO: 885056-96-2
• Molecular Weight: 207.659
• Mol File: 885056-96-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 5-chloro-2-(pyrrol-1-yl)benzyl alcohol(CAS DataBase Reference)
• NIST Chemistry Reference: 5-chloro-2-(pyrrol-1-yl)benzyl alcohol(885056-96-2)
• EPA Substance Registry System: 5-chloro-2-(pyrrol-1-yl)benzyl alcohol(885056-96-2)

Safety Data

• Hazardous Substances Data: 885056-96-2(Hazardous Substances Data)

Upstream product

• 885056-95-1 ethyl 5-chloro-2-(pyrrol-1-yl)benzoate 
• 63243-75-4 ethyl 2-amino-5-chlorobenzoate 
• 88442-97-1 methyl 4-chloro-2-(1H-pyrrol-1-yl)benzoate 
• 5202-89-1 4-chlorobenzenesulfonyl chloride 
• 96515-79-6 5-chloro-2-fluorobenzaldehyde 

Downstream Products

• 1092501-85-3 1-(4-chloro-2-(chloromethyl)phenyl)-1H-pyrrole 
• 1604835-50-8 N-(benzo[d][1,3]dioxol-5-ylmethyl)-N-{2-(tert-butylamino)-1-[5-chloro-2-(1H-pyrrol-1-yl)phenyl]-2-oxoethyl}but-2-ynamide 
• 1604835-51-9 N-{2-(tert-butylamino)-1-[5-chloro-2-(1H-pyrrol-1-yl)phenyl]-2-oxoethyl}-N-(4-methoxybenzyl)pent-2-ynamide 
• 1604835-52-0 N-{2-(tert-butylamino)-1-[5-chloro-2-(1H-pyrrol-1-yl)phenyl]-2-oxoethyl}-N-(4-methoxybenzyl)but-2-ynamide 
• 1604835-54-2 N-{2-(butylamino)-1-[5-chloro-2-(1H-pyrrol-1-yl)phenyl]-2-oxoethyl}-N-(4-methoxybenzyl)-3-phenylpropiolamide 
• 1604835-37-1 (Z)-N-(tert-butyl)-3-chloro-9-ethyl-6-(4-methoxybenzyl)-7-oxo-6,7-dihydro-5H-benzo[b]pyrrolo[2,1-i][1,5]diazonine-5-carboxamide 
• 1604835-38-2 (Z)-N-(tert-butyl)-3-chloro-6-(4-methoxybenzyl)-9-methyl-7-oxo-6,7-dihydro-5H-benzo[b]pyrrolo[2,1-i][1,5]diazonine-5-carboxamide 
• 941306-24-7 (6-chloro-3a-aza-cyclopenta[a]inden-8-ylidene)-phenyl-amine 
• 885056-97-3 5-chloro-2-(1H-pyrrol-1-yl)benzaldehyde 

Relevant articles and documents

Bronsted Acid Catalyzed Cyclization of Inert N-Substituted Pyrroles to Benzo[ f ]pyrrolo[1,2- a ][1,4]diazepines

Two approaches involving intramolecular and intermolecular cyclization, respectively, have been developed for the direct and practical construction of a series of important benzo[ f ]pyrrolo[1,2- a ][1,4]azepines by using Bronsted acid catalysts. Upon catalysis by TsOH, the intramolecular dehydroxylation/ring closure of 3-hydroxy-2-[2-(1 H -pyrrol-1-yl)benzyl]isoindolin-1-ones provided various racemic benzo[ f ]pyrrolo[1,2- a ][1,4]azepines in high yields. Furthermore, enantioenriched benzo[ f ]pyrrolo[1,2- a ][1,4]azepines were also obtained by chiral phosphoric acid catalyzed intermolecular addition of [2-(1 H -pyrrol-1-yl)phenyl]methanamines to 2-formylbenzoates under mild conditions.

Regioselective synthesis of diversely substituted diazoninones through a post-Ugi gold-catalyzed intramolecular hydroarylation process

A highly efficient approach for the regioselective construction of fused nine-membered rings (diazoninone framework) was developed by employing sequential Ugi and gold-catalyzed intramolecular hydroarylation reactions. The scope of this intramolecular cyc

Synthesis of 9-arylamino- and (Z)-9-arylimino-9H-pyrrolo[1,2-a]indoles by reactions of 2-(pyrrol-1-yl)benzaldehydes with aryl amines

Heating mixtures of 2-(pyrrol-1-yl)benzaldehydes and aryl amines under argon afforded 9-arylamino-9H-pyrrolo[1,2-a]indoles, via cyclization of the resulting 2-(pyrrol-1-yl)benzaldimine intermediates. Heating in the presence of oxygen afforded (Z)-9-arylim