88708-54-7

Basic information

• Product Name: Benzene, [2-(dodecylthio)ethenyl]-, (E)-
• CAS NO: 88708-54-7
• Molecular Formula: C20H32S
• Molecular Weight: 304.54
• Mol File: 88708-54-7.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: Benzene, [2-(dodecylthio)ethenyl]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [2-(dodecylthio)ethenyl]-, (E)-(88708-54-7)
• EPA Substance Registry System: Benzene, [2-(dodecylthio)ethenyl]-, (E)-(88708-54-7)

Safety Data

• Hazardous Substances Data: 88708-54-7(Hazardous Substances Data)

Upstream product

• 103-64-0 bromostyrene 
• 112-55-0 1-dodecylthiol 
• 637-44-5 phenylpropyolic acid 
• 2757-37-1 didodecyl disulfide 
• 588-72-7 [(E)-2-bromoethenyl]benzene 
• 536-74-3 phenylacetylene 
• 1034014-59-9 1-(dodec-1-ylsulfanyl)-2-phenylethyne 

Downstream Products

• 15325-61-8 (E)-(3-methylbut-1-en-1-yl)benzene 
• 18869-27-7 (E)-(2-cyclohexylvinyl)benzene 
• 7206-28-2 (Z)-dodec-5-ene 
• 7206-16-8 (E)-dodec-5-ene 
• 15325-54-9 (Z)-hex-1-en-1-ylbenzene 
• 6111-82-6 (E)-1-phenyl-1-hexene 
• 40132-69-2 (Z )-1-(2-cyclohexyl-1-ethenyl)benzene 

Relevant articles and documents

Efficient visible light initiated hydrothiolations of alkenes/alkynes over Ir2S3/ZnIn2S4: Role of Ir2S3

The hydrothiolations of alkynes/alkenes with thiols is an atom-economic and thus attractive method for the constructions of C-S bonds. Here Ir2S3/ZnIn2S4 nanocomposites with varied Ir2S3 loadings were obtained by one-pot solvothermal method from ZnCl2, InCl3 and thioacetamide with IrCl3. The loading of Ir2S3 on the surface of ZnIn2S4 promoted the hydrothiolations of alkenes and alkynes, with an optimum performance observed over 0.5 molpercent Ir2S3/ZnIn2S4 nanocomposite. Based on the studies on the performance of several other cocatalysts (MoS2, NiS and Pd) loaded ZnIn2S4 and the EIS analyses, it was proposed that the superior performance over Ir2S3/ZnIn2S4 nanocomposite can be ascribed to an improved efficiency on the photogeneration of the thiyl radicals by loading Ir2S3 as well as its inactivity for photocatalytic hydrogen evolution, a side reaction in the light initiated hydrothiolation reaction over ZnIn2S4. This study not only demonstrates an efficient and green strategy to synthesize thiolated products under visible light based on semiconductor photocatalysis, but also provides some guidances for the design and development of photocatalytic systems for light induced organic syntheses.

Convenient and Efficient Diastereoselective Preparation of Functionalized Z-Alkenyl Sulfides

We have developed an efficient and convenient regio- and stereoselective reduction of the alkynyl sulfides with pinacolborane in the presence of copper(I) chloride to produce (Z)-alkenyl sulfides in good and very good yields. The functionalized alkynyl sulfides are readily available based on the reaction of lithium acetylides with thiotosylates under mild conditions.

Sulfamic acid: An efficient and recyclable catalyst for the regioselective hydrothiolation of terminal alkenes and alkynes with thiols

Herein, we described a new method for the preparation of thioethers through hydrothiolation of alkenes and alkynes, using sulfamic acid as a reusable catalyst. Generally, this new methodology afforded the desired products in very good yields, under metal