889129-99-1

Basic information

• Product Name: ethyl (Z)-3-(dimethyl(phenyl)silyl)-3-phenyl-2-propenoate
• Synonyms: ethyl (Z)-3-(dimethyl(phenyl)silyl)-3-phenyl-2-propenoate
• CAS NO: 889129-99-1
• Molecular Weight: 310.468
• Mol File: 889129-99-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ethyl (Z)-3-(dimethyl(phenyl)silyl)-3-phenyl-2-propenoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl (Z)-3-(dimethyl(phenyl)silyl)-3-phenyl-2-propenoate(889129-99-1)
• EPA Substance Registry System: ethyl (Z)-3-(dimethyl(phenyl)silyl)-3-phenyl-2-propenoate(889129-99-1)

Safety Data

• Hazardous Substances Data: 889129-99-1(Hazardous Substances Data)

Upstream product

• 17909-55-6 (α,α-dibromobenzyl)dimethylphenylsilane 
• 100-44-7 benzyl chloride 
• 98-88-4 benzoyl chloride 
• 1468-28-6 4-benzoylmorpholine 
• 4071-88-9 trimethylsilanyl-acetic acid ethyl ester 
• 17909-51-2 (dimethyl(phenyl)silyl)(phenyl)methanone 

Downstream Products

• 889130-06-7 (R)-3-(dimethylphenylsilyl)-3-phenylpropanoic acid ethyl ester 
• 72656-47-4 ethyl (R)-3-hydroxy-3-phenylpropanoate 
• 153221-16-0 (R)-3-(dimethylphenylsilyl)-3-(phenyl)propanoic acid 
• 144452-46-0 β-Dimethylphenylsilyl-β-phenyl propanoyl chloride 
• 67263-05-2 (S)-3-(dimethylphenylsilyl)-3-phenylpropanoic acid ethyl ester 

Relevant articles and documents

Enantioselective Synthesis of Chiral 3-Substituted-3-silylpropionic Esters via Rhodium/Bisphosphine-Thiourea-Catalyzed Asymmetric Hydrogenation

We have successfully developed the asymmetric hydrogenation of β-silyl-α,β-unsaturated esters to prepare chiral 3-substituted-3-silylpropionic ester products catalyzed by rhodium/bisphosphine-thiourea (ZhaoPhos) with excellent results (up to 97% yield, >99% ee, 1500 TON). Moreover, our hydrogenation products can be efficiently converted to other important organic molecules, such as chiral ethyl (R)-3-hydroxy-3-phenylpropanoate or (R)-3-[dimethyl(phenyl)silyl]-3-phenylpropanoic acid. (Figure presented.).