889862-10-6

Basic information

• Product Name: trans-1-benzylsulfonyl-2-(4-fluorophenyl)ethene
• Synonyms: trans-1-benzylsulfonyl-2-(4-fluorophenyl)ethene
• CAS NO: 889862-10-6
• Molecular Weight: 276.331
• Mol File: 889862-10-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-1-benzylsulfonyl-2-(4-fluorophenyl)ethene(CAS DataBase Reference)
• NIST Chemistry Reference: trans-1-benzylsulfonyl-2-(4-fluorophenyl)ethene(889862-10-6)
• EPA Substance Registry System: trans-1-benzylsulfonyl-2-(4-fluorophenyl)ethene(889862-10-6)

Safety Data

• Hazardous Substances Data: 889862-10-6(Hazardous Substances Data)

Upstream product

• 459-57-4 4-fluorobenzaldehyde 
• 203664-74-8 diethyl benzylsulfonylmethylphosphonate 

Downstream Products

• 134747-51-6 trans-1-(4-fluorophenyl)-3-phenylprop-2-en-1-ol 

Relevant articles and documents

The epoxy-Ramberg-Baecklund reaction (ERBR): A sulfone-based method for the synthesis of allylic alcohols

The epoxy-Ramberg-Baecklund reaction (ERBR) is outlined, in which α,β-epoxy sulfones are converted into a range of mono-, di- and tri-substituted allylic alcohols, on treatment with base. Modification of this method enabled the preparation of enantio-enriched allylic alcohols following the diastereoselective epoxidation of enantio-enriched vinyl sulfones that were accessed efficiently from the chiral pool. The scope, optimisation and limitations of the ERBR as a method for the preparation of allylic alcohols are discussed. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.