890522-63-1

Basic information

• Product Name: 3-fluorobenzenesulfonohydrazide
• Synonyms: 3-fluorobenzenesulfonohydrazide
• CAS NO: 890522-63-1
• Molecular Weight: 190.198
• Mol File: 890522-63-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 3-fluorobenzenesulfonohydrazide(CAS DataBase Reference)
• NIST Chemistry Reference: 3-fluorobenzenesulfonohydrazide(890522-63-1)
• EPA Substance Registry System: 3-fluorobenzenesulfonohydrazide(890522-63-1)

Safety Data

• Hazardous Substances Data: 890522-63-1(Hazardous Substances Data)

Upstream product

• 701-27-9 3-fluorobenzene-1-sulfonyl chloride 

Downstream Products

• 455-36-7 1-(3-fluorophenyl)ethanone 
• 1394827-36-1 3-(3-fluorophenyl)indolizine-1-carbonitrile 
• 1620220-68-9 3-(((3-fluorophenyl)sulfonyl)methyl)-1,3-dimethylindolin-2-one 
• 1161823-22-8 1,3,7-trimethyl-8-(m-fluorophenyl)-xanthine 

Relevant articles and documents

Palladium-catalyzed allylation of sulfonyl hydrazides with alkynes to synthesize allylic arylsulfones

A novel method for the construction of allyl arylsulfone derivatives was developed by palladium catalyzed allylation of sulfonyl hydrazides with alkynes. A series of structurally diverse allyl arylsulfones can be regioselectively synthesized in high yields under mild conditions.

NaHSO3-Mediated Direct Synthesis of Sulfinic Esters from Sulfonyl Hydrazides under Transition-Metal-Free Conditions

We have developed a protocol for the NaHSO3-promoted esterification of sulfonyl hydrazides with alcohols for the synthesis of sulfinic esters. Various sulfonyl hydrazides could be converted to the corresponding sulfinic esters in good to high yields. The merits of this protocol include mild transition-metal-free reaction conditions, an inexpensive and available reagent, and operational simplicity. Controlled experiments reveal that this transformation probably undergoes via a radical pathway. (Figure presented.).