89284-52-6Relevant articles and documents
Energy-level tuning of poly(p-phenylenebutadiynylene) derivatives by click chemistry-type postfunctionalization of side-chain alkynes
Wang, Dong,Zhang, Ruirui,Gao, Hong,Wang, Xiangke,Wang, Huihui,Yang, Zhou,He, Wanli,Cao, Hui,Gu, Jianming,Hu, Huiying,Yang, Huai
, p. 114 - 121 (2016)
A series of poly(p-phenylenebutadiynylene) polymers substituted with electron-rich alkynes as the side chain were synthesized by homocoupling polymerization of asymmetric bifunctional monomers. The electron-rich alkynes underwent "click chemistry" with te
Functional phenylethynylene side arm poly(arylene ethynylene) conjugated polymers: Optical and electrochemical behavior for enrichment of electronic applications
Arun Kumar,Gomathi Priya,Alagar
, p. 5767 - 5773 (2018/04/23)
The poly(arylene ethynylene) (PAE) conjugated polymers (CPs) with a donor-acceptor (D-A) side arm have been designed and synthesized using Sonogashira cross coupling in the presence of cyano methylene, or cyano thiophene gave diethynyl (A) and alkoxy and alkyl substituted diiodo aryl monomers (D). An interesting electronic response in optical measurements such as UV-visible (UV-vis) and fluorescence (FL) spectra was observed in tetrahydrofuran solvent. From the FL spectra, it was observed that the CP solutions possess an interesting long bathochromic shift when compared with the UV-vis spectra, because of the electron withdrawing, electron releasing and conjugation effects. The electrochemical and thin film UV-vis spectral measurements provided highest occupied molecular orbital-lowest unoccupied molecular orbital (HOMO-LUMO) electronic energy levels and their corresponding semiconducting electronic energy gaps (Eg) of the PAE CPs. Among the side arm CPs, polymers P1 and P5 have low Eg of 2.14 eV and 2.17 eV. The new PAE CPs are reliable for use in electronic and photonics applications.
The invention relates to a five-membered ring is connected to the core of the asymmetric dye molecule and its preparation method (by machine translation)
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Paragraph 0024; 0025; 0026; 0035; 0044, (2018/01/19)
A category of connected five-membered ring as the center of the asymmetric dye molecule and its preparation method, the dye molecules is the major feature of the structure of the peripheral introduction through asymmetric strong electron-donating groups with strong electron withdrawing group and choose to model the availability of five-membered ring as its rigid central, greatly enhances the overall its molecule conjugated effect, expands the range of absorbing in a visible light range with the absorption intensity. The preparation of the dye molecule has a very good thermal stability and chemical stability, low-cost, high-efficiency, simple manufacturing process, excited state life long, can be used as a dye sensitizing agent is applied to the dye-sensitized solar cell, and can exhibit good photoelectric conversion performance, in the new energy development in the use and has broad application prospects in the photoelectric device in the use of a great potential. (by machine translation)