89363-81-5

Basic information

• Product Name: Benzene, 1,4-dimethoxy-2-(phenylthio)-
• CAS NO: 89363-81-5
• Molecular Formula: C14H14O2S
• Molecular Weight: 246.33
• Mol File: 89363-81-5.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Benzene, 1,4-dimethoxy-2-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,4-dimethoxy-2-(phenylthio)-(89363-81-5)
• EPA Substance Registry System: Benzene, 1,4-dimethoxy-2-(phenylthio)-(89363-81-5)

Safety Data

• Hazardous Substances Data: 89363-81-5(Hazardous Substances Data)

Upstream product

• 1483-27-8 2,5-dimethoxythiophenol 
• 98-80-6 phenylboronic acid 
• 882-33-7 diphenyldisulfane 
• 102-56-7 2,5-dimethoxyaniline 
• 107099-99-0 2,5-dimethoxyphenylboronic acid 
• 108-98-5 thiophenol 
• 150-78-7 1,4-dimethoxybezene 
• 591-50-4 iodobenzene 
• 108-86-1 bromobenzene 
• 18231-96-4 2-(phenylthio)benzene-1,4-diol 
• 74-88-4 methyl iodide 
• 1126-80-3 (n-butylthio)benzene 
• 77-78-1 dimethyl sulfate 
• 89363-72-4 C₁₈H₂₃O₂S⁽¹⁺⁾*BF₄^(1-) 

Downstream Products

• 1310713-30-4 2,2′,5,5′-tetramethoxy-4,4′-bis(phenylsulfanyl)biphenyl 
• 1310713-51-9 4,4′-bis(phenylsulfanyl)-2,2′,5,5′-tetrahydroxybiphenyl 
• 1310713-56-4 C₂₄H₁₄O₄S₂ 
• 1536350-07-8 C₅₈H₅₄N₈O₁₀S₂ 
• 1536350-01-2 4,4′-bis(phenylsulfanyl)-2,2′-dihydroxy-5,5′-dipropargyloxybiphenyl 
• 1536349-99-1 2,10-dipropargyloxy-6,6-dimethyl-3,9-bis(phenylthio)dibenzo[d,f][1,3]dioxepine 
• 1536349-88-8 4,4′-bis(phenylsulfanyl)-2,2′-dihydroxy-5,5′-di(methoxymethyloxy)biphenyl 
• 1536349-83-3 6,6-di-tert-butyl-2,10-bis(methoxymethoxy)-3,9-bis(phenylthio)dibenzo[d,f][1,3,2]dioxasilepine 
• 1455435-74-1 6,6-di-tert-butyl-3,9-bis(phenylthio)dibenzo-[d,f][1,3,2]dioxasilepine-2,10-diol 
• 1536348-94-3 6,6-dimethyl-3,9-bis(phenylthio)dibenzo[d,f][1,3]dioxepine-2,10-diol 
• 1536348-91-0 2,2′,5,5′-tetramethoxy-4,4′-bis(phenylsulfonyl)biphenyl 
• 108-98-5 thiophenol 
• 882-33-7 diphenyldisulfane 
• 150-78-7 1,4-dimethoxybezene 

Relevant articles and documents

Room temperature nickel-catalyzed cross-coupling of aryl-boronic acids with thiophenols: Synthesis of diarylsulfides

A NiCl2/2,2′-bipyridine-catalyzed cross-coupling of thiophenols with arylboronic acids has been developed for the synthesis of symmetric and unsymmetric diarylsulfides at room temperature and in air. This methodology is reliable and offers a mild and easy to operate process for the synthesis of arylthioethers, which are essential compounds with applications in the pharmaceutical and agricultural industries. This method avoids the use of expensive transition metals, such as Pd, Ir or Rh, sophisticated ligands and elevated temperatures. It also has a wide substrate scope (55 examples) and provides products in good to excellent yields (72-93%).

4,4′-diarylsulfanyl-2,2′,5,5′-tetraoxybiaryl derivatives as a water-soluble fluorescent dye

4,4′-Disulfanyl-2,2′,5,5′-tetrahydrobiaryl (5,5′-disulfanyl hydroquinone dimer) derivatives were readily synthesized from benzoquinone and thiols via an oxidative coupling reaction. The hydroquinone dimers showed strong fluorescence upon excitation at 330

Silver catalyzed C-C and C-S coupling of aryl halides and thiols with boronic acids

An efficient Ag(I) catalyzed carbon-carbon and carbon-sulfur bond formation reaction of aryl halides and thiols with boronic acids has been demonstrated. Using this protocol, substrates with a wide range of functional group including electron-rich, and electron deficient substituents have been explored. These reactions are particularly useful to prepare symmetrical and unsymmetrical biphenyls and thioethers. These products were isolated in high yield.