89619-10-3

Basic information

• Product Name: 1-(1-BROMOVINYL)-4-CHLOROBENZENE, 90%
• Synonyms: 1-(1-BroMovinyl)-4-chlorobenzene 90%
• CAS NO: 89619-10-3
• Molecular Formula: C₈H₆BrCl
• Molecular Weight: 217.49
• Product Categories: Alkenes;Aryl;Boronic Acids;Organic Building Blocks;AcyclicBoronic Acids and Derivatives
• Mol File: 89619-10-3.mol
• Article Data: 17

Chemical Properties

• Boiling Point: 263.1°C at 760 mmHg
• Flash Point: 110 °C
• Appearance: /
• Density: 1.539 g/mL at 25 °C
• Vapor Pressure: 0.0171mmHg at 25°C
• Refractive Index: n20/D 1.605
• CAS DataBase Reference: 1-(1-BROMOVINYL)-4-CHLOROBENZENE, 90%(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(1-BROMOVINYL)-4-CHLOROBENZENE, 90%(89619-10-3)
• EPA Substance Registry System: 1-(1-BROMOVINYL)-4-CHLOROBENZENE, 90%(89619-10-3)

Safety Data

• Hazard Codes: Xn,N
• Statements: 22-37/38-41-51/53
• Safety Statements: 26-36/37/39-61
• RIDADR: UN 3082 9/PG 3
• WGK Germany: 3
• Hazardous Substances Data: 89619-10-3(Hazardous Substances Data)

Usage

Description

1-(1-Bromovinyl)-4-chlorobenzene, 90% is a halogenated benzene derivative that consists predominantly of the compound 1-(1-Bromovinyl)-4-chlorobenzene. It is 90% pure, indicating a high level of concentration. This chemical features a bromine atom and a vinyl group attached to the benzene ring, along with a chlorine substituent. Due to its flammable nature, it should be handled with care in a controlled laboratory environment.

Uses

Used in Organic Synthesis:
1-(1-Bromovinyl)-4-chlorobenzene, 90% is used as a building block in organic synthesis for the production of various other chemical compounds. Its unique structure with a bromine atom, vinyl group, and chlorine substituent allows it to be a versatile component in creating a range of different organic molecules.
Used in Chemical Production:
In the chemical production industry, 1-(1-Bromovinyl)-4-chlorobenzene, 90% serves as an important intermediate in the synthesis of various chemicals. Its presence in the production process can lead to the development of new compounds with specific properties and applications, making it a valuable asset in the chemical manufacturing sector.

InChI:InChI=1/C8H6BrCl/c1-6(9)7-2-4-8(10)5-3-7/h2-5H,1H2

Upstream product

• 873-73-4 4-n-chlorophenylacetylene 
• 74-95-3 1,1-dibromomethane 
• 99-91-2 para-chloroacetophenone 
• 75230-50-1 p-chloroacetophenone tosylhydrazone 
• 1073-67-2 4-vinylbenzyl chloride 
• 23135-16-2 1,2-dibromo-1-(4-chlorophenyl)ethane 
• 187409-10-5 3-chloro-α,β-dibromoethylbenzene 

Downstream Products

• 45941-96-6 2-(4-chlorophenyl)-3-hydroxypropene 
• 536-38-9 4-chlorobenzoylmethyl bromide 
• 53503-49-4 ethyl 4-(4-chlorophenyl)-4-oxobutanoate 

Relevant articles and documents

Absence of Intermediates in the BINOL-Derived Mg(II)/Phosphate-Catalyzed Desymmetrizative Ring Expansion of 1-Vinylcyclobutanols

The catalyzed desymmetrizative ring expansion of alkenylcyclobutanols promoted by halofunctionalization of the alkene moiety with N-bromosuccinimide has been experimentally and computationally studied. The reaction yields highly enantioenriched cyclopenta

Catalytic Asymmetric Halogenation/Semipinacol Rearrangement of 3-Hydroxyl-3-vinyl Oxindoles: A Stereodivergent Kinetic Resolution Process

A highly enantioselective halogenation/semipinacol rearrangement of isatin-derived allylic alcohols has been developed with a chiral N,N′-dioxide/ScIII complex as catalyst. This strategy involved a pivotal stereodivergent kinetic resolution process and provided a facile and efficient entry to optically active halo-substituted quinolone derivatives and quinoline alkaloids with a quaternary stereocenter simultaneously under mild reaction conditions. Based on the control experiments together with kinetic studies and DFT calculations, a possible catalytic cycle was proposed to illustrate the reaction process and enantiocontrol.

Electrochemical Semipinacol Rearrangements of Allylic Alcohols: Construction of All-Carbon Quaternary Stereocenters

The first examples of electrochemical trifluoromethylation and sulfonylation/semipinacol rearrangements of allylic alcohols were developed using cheap and stable RSO2Na (R = CF3, Ph) as reagents. Various β-trifluoromethyl and sulfonated ketones were obtained in moderate to excellent yields. This strategy provides a facile, direct, and complementary approach to construct all-carbon quaternary stereocenters. In addition, the reaction has the advantages of being chemical oxidant-free and metal-free and has safe and mild reaction conditions.