23135-16-2

Basic information

• Product Name: 1-CHLORO-4-(1,2-DIBROMOETHYL)BENZENE
• Synonyms: 1-Chloro-4-(1,2-dibromoethyl)benzene;1-Chloro-4-(a,b-dibromoethyl)benzene
• CAS NO: 23135-16-2
• Molecular Formula: C₈H₇Br₂Cl
• Molecular Weight: 298.4
• Product Categories: Aryl;C8;Halogenated Hydrocarbons
• Mol File: 23135-16-2.mol
• Article Data: 35

Chemical Properties

• Melting Point: 45-49 °C
• Boiling Point: 289.7°C at 760 mmHg
• Flash Point: 110 °C
• Appearance: /
• Density: 1.849g/cm³
• Vapor Pressure: 0.00376mmHg at 25°C
• Refractive Index: 1.613
• CAS DataBase Reference: 1-CHLORO-4-(1,2-DIBROMOETHYL)BENZENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-CHLORO-4-(1,2-DIBROMOETHYL)BENZENE(23135-16-2)
• EPA Substance Registry System: 1-CHLORO-4-(1,2-DIBROMOETHYL)BENZENE(23135-16-2)

Safety Data

• Hazard Codes: Xi,N
• Statements: 36/37/38-51/53
• Safety Statements: 26-61
• RIDADR: UN 3077 9/PG 3
• WGK Germany: 3
• Hazardous Substances Data: 23135-16-2(Hazardous Substances Data)

Usage

Uses

1-Chloro-4-(1,2-dibromoethyl)benzene

InChI:InChI=1/C8H7Br2Cl/c9-5-8(10)6-1-3-7(11)4-2-6/h1-4,8H,5H2

Upstream product

• 622-98-0 4-chloro(ethylbenzene) 
• 104-88-1 4-chlorobenzaldehyde 
• 1073-67-2 4-vinylbenzyl chloride 
• 75-62-7 Bromotrichloromethane 
• 67-56-1 methanol 
• 201230-82-2 carbon monoxide 

Downstream Products

• 6314-52-9 2-bromo-1-(4-chlorophenyl)ethanol 
• 1073-67-2 4-vinylbenzyl chloride 
• 873-73-4 4-n-chlorophenylacetylene 
• 38922-74-6 2-(4-chlorophenyl)imidazolo[1,2-a]pyridine 
• 65964-62-7 2-(4-chlorophenyl)-7-methyl-imidazo[1,2-a]pyridine 
• 61001-05-6 2-(4-chlorophenyl)imidazo[2,1-a]isoquinoline 
• 1414365-79-9 1-benzyl-4-(4-chlorophenyl)-2-phenyl-1H-imidazole 
• 536-38-9 4-chlorobenzoylmethyl bromide 
• 89619-10-3 1-(1-bromovinyl)-4-chlorobenzene 
• 32687-35-7 3-(4-chlorophenyl)-2H-azirine 
• 197785-44-7 1-(1-azido-2-bromoethyl)-4-chlorobenzene 

Relevant articles and documents

A General Method for the Dibromination of Vicinal sp3C-H Bonds Exploiting Weak Solvent-Substrate Noncovalent Interactions

A general procedure of 1,2-dibromination of vicinal sp3 C-H bonds of arylethanes using N-bromosuccinimide as the bromide reagent without an external initiator has been established. The modulation of the strength of the intermolecular noncovalent interactions between the solvent and arylethane ethanes, quantitatively evaluated via quantum chemical calculations, allows us to circumvent the fact that arylethane ethane cannot be dibrominated through traditional methods. The mechanism was explored by both experiments and quantum chemical calculations, revealing a radical chain with HAA process.

Dibrominated addition and substitution of alkenes catalyzed by Mn2(CO)10

A practical method for the dibromination of alkenes without using molecular bromine is consistently appealing in organic synthesis. Herein, we report Mn-catalyzed dibrominated addition and substitution of alkenes only with N-bromosuccinimide, producing a variety of synthetically valuable dibrominated compounds in moderate to high yields. This journal is

Photoredox-catalyzed synthesis of N-unsubstituted enaminosulfones from vinyl azides and sulfinates

A metal-free visible light photoredox-catalyzed synthesis of N-unsubstituted enaminosulfones from vinyl azides and sodium sulfinates in moderate to high yields is described. The reaction proceeds in ethanol and uses eosin Y as a readily available photocatalyst in combination with nitrobenzene as an electron shuttle. Taking into account the number of steps involved (generation of the sulfonyl radical, its addition to the double bond, elimination of molecular nitrogen with formation of an iminyl radical, followed by its reduction and protonation) as well as the number of redox-active reaction partners involved, the selectivity of the process is quite impressive.