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90220-32-9

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90220-32-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 90220-32-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,0,2,2 and 0 respectively; the second part has 2 digits, 3 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 90220-32:
(7*9)+(6*0)+(5*2)+(4*2)+(3*0)+(2*3)+(1*2)=89
89 % 10 = 9
So 90220-32-9 is a valid CAS Registry Number.

90220-32-9Downstream Products

90220-32-9Relevant articles and documents

Solution and Flash Vacuum Pyrolyses of 3-Arylpropanesulfonyl and 2-(Aryloxy)ethanesulfonyl Azides. Synthesis of 7-Membered Sultams

Abramovitch, Rudolph A.,Kress, Albert O.,McManus, Samuel P.,Smith, Maurice R.

, p. 3114 - 3121 (2007/10/02)

The solution and flash vacuum pyrolyses of 3-arylpropanesulfonyl azides have been studied and the results compared with those of the corresponding 2-arylethanesulfonyl azides.The best yields of 7-membered ring sultams are formed on solution decomposition in Freon 113.Hydrogen abstraction and solvent insertion products are obtained mainly in hydrocarbon solvents.The structure of the 7-membered sultams have been established unambiguously and an authentic sample of the parent 2,3,4,5-tetrahydro-1,2-thiazepine 1,1-dioxide prepared.Decomposition of 3-(2,6-dichlorophenyl)propanesulfonyl azide (22) leads to a 6,9-dichloro sultam (33c) via a 1,2-chlorine shift.FVP of 3-(2-mesityl)propanesulfonyl azide (20) gave a good yield of the 7-membered ring sultam (34)(1,2-methyl shift).FVP of 3-phenyl-1-propanesulfonyl azide (16) at 995 deg C (0.05 mm) gave, among other products, a 6.2percent yield of 5,6,7,8-tetrahydroquinoline (39).The formation of these products is discussed.Thermolysis of 2-(aryloxy)ethanesulfonyl azides gave the corresponding 7-membered ring sultams 27 as well.

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