90496-14-3

Basic information

• Product Name: 1-Butanamine, N-(3-phenylpropylidene)-
• CAS NO: 90496-14-3
• Molecular Formula: C13H19N
• Molecular Weight: 189.301
• Mol File: 90496-14-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1-Butanamine, N-(3-phenylpropylidene)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Butanamine, N-(3-phenylpropylidene)-(90496-14-3)
• EPA Substance Registry System: 1-Butanamine, N-(3-phenylpropylidene)-(90496-14-3)

Safety Data

• Hazardous Substances Data: 90496-14-3(Hazardous Substances Data)

Usage

Chemical category

Amines Organic compounds derived from ammonia.

Structure

Contains a 1-butanamine group (four carbon atoms and a nitrogen atom) and a phenylpropylidene group (a phenyl ring and a propylidene chain).

Industrial applications

Used as a precursor in the synthesis of pharmaceuticals, agrochemicals, and other organic compounds.

Potential use

Building block in the production of specialty chemicals and materials.

Chemical structure

The compound's chemical structure and properties make it suitable for a wide range of applications in the chemical industry.

Functional groups

Amine (-NH2) and phenylpropylidene (C6H5-CH=CH-CH2-).

Molecular weight

Approximately 189.28 g/mol.

Appearance

Likely a colorless to light-colored liquid or solid, depending on the temperature.

Solubility

Soluble in organic solvents such as ethanol, methanol, and acetone.

Reactivity

Can react with acids, bases, and other compounds containing reactive functional groups.

Stability

Stable under normal temperature and pressure conditions, but may decompose upon exposure to heat, light, or strong oxidizing agents.

Hazards

Potential irritant, harmful if inhaled, swallowed, or absorbed through the skin. Proper handling and storage are necessary to minimize risks.

Regulatory status

May be subject to specific regulations and guidelines depending on the intended use and location.

Environmental impact

Potential environmental hazards if not disposed of or used properly, due to its chemical properties and potential reactivity with other substances.

Upstream product

• 122-97-4 3-Phenyl-1-propanol 
• 109-73-9 N-butylamine 
• 104-53-0 3-phenyl-propionaldehyde 
• 645-59-0 dihydrocinnamonitrile 

Downstream Products

• 40419-15-6 1-(n-Butylamino)-1,3-diphenylpropan 
• 90496-16-5 Butyl-(1-phenethyl-pentyl)-amine 
• 68164-02-3 N-butyl-(1-methyl-3-phenyl)propylamine 
• 92111-13-2 PPC₄ 
• 90496-17-6 Butyl-(1-phenethyl-3-phenyl-propyl)-amine 

Relevant articles and documents

Poisoning effect of N-containing compounds on performance of Raney nickel in transfer hydrogenation

The effect of amines, imines and heterocycle compounds on conversion has been studied in transfer hydrogenation of camphor and 2-PrOH catalyzed by Raney nickel. Small amount (5 mol% to nickel) of N-containing compound significantly decreases catalyst activity. It has been shown that the poisoning effect mostly depends on molecular size of amines and heterocyclic compounds. For aniline and cyclohexylamine the dependence of camphor conversion on poison/nickel ratio was obtained. Additionally, benzaldehyde, cinnamaldehyde demonstrated higher reactivity compared corresponding imines under transfer hydrogenation conditions. Obtained data explain low activity of nickel-based catalysts when N-containing compounds are presented in reaction mixture.

Practical Synthesis of Amides via Copper/ABNO-Catalyzed Aerobic Oxidative Coupling of Alcohols and Amines

A modular Cu/ABNO catalyst system has been identified that enables efficient aerobic oxidative coupling of alcohols and amines to amides. All four permutations of benzylic/aliphatic alcohols and primary/secondary amines are viable in this reaction, enabling broad access to secondary and tertiary amides. The reactions exhibit excellent functional group compatibility and are complete within 30 min-3 h at rt. All components of the catalyst system are commercially available.

The addition of amines to diisobutylaluminum-imine complexes. Preparation of NPS R-568 hydrochloride

A facile procedure for the preparation of secondary and tertiary amines from nitriles has been developed. The addition of amines to diisobutylaluminum-imine complexes derived by treating nitriles with DIBAL-H was found to proceed in moderate to good yield