907-04-0

Basic information

• Product Name: bis-(trans-4-tert-butyl-cyclohexanecarbonyl)-peroxide
• Synonyms: bis-(trans-4-tert-butyl-cyclohexanecarbonyl)-peroxide
• CAS NO: 907-04-0
• Molecular Weight: 366.541
• Mol File: 907-04-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis-(trans-4-tert-butyl-cyclohexanecarbonyl)-peroxide(CAS DataBase Reference)
• NIST Chemistry Reference: bis-(trans-4-tert-butyl-cyclohexanecarbonyl)-peroxide(907-04-0)
• EPA Substance Registry System: bis-(trans-4-tert-butyl-cyclohexanecarbonyl)-peroxide(907-04-0)

Safety Data

• Hazardous Substances Data: 907-04-0(Hazardous Substances Data)

Upstream product

• 28467-42-7 trans-4-t-butylcyclohexanecarbonyl chloride 
• 28467-41-6 cis-4-tert-butylcyclohexanecarboxylic acid chloride 
• 98-73-7 4-(1,1-dimethylethyl)benzoic acid 
• 943-28-2 cis-4-t-butylcyclohexanecarboxylic acid 
• 5451-55-8 4-tert-butylcyclohexanecarboxylic acid 
• 5009-36-9 cis-1-bromo-4-tert-butylcyclohexane 
• 98-52-2 4-(1,1-dimethylethyl)-cyclohexanol 
• 943-29-3 trans-4-(tert-butyl)cyclohexane-1-carboxylic acid 

Downstream Products

• 124-38-9 carbon dioxide 
• 5009-37-0 trans-1-bromo-4-tert-butylcyclohexane 
• 5009-36-9 cis-1-bromo-4-tert-butylcyclohexane 
• 53119-08-7 cis-4-tert-butyl-cyclohexanecarboxylic acid-(cis-4-tert-butyl-cyclohexyl ester) 
• 3178-22-1 tert-butylcyclohexane 
• 2228-98-0 4-tert-butylcylohexene 

Relevant articles and documents

Stereoelectronic Effects in Hydrogen-atom Transfer Reactions of Substituted Cyclohexyl Radicals

Thermolysis of the peroxyoxalates (1)-(7) and the diacyl peroxides (8)-(11) in cyclohexane at 100 deg C gives cycloalkenes and cycloalkanes by hydrogen-atom transfer reactions of the initially formed conformationally biased 4-t-butyl-, 4-t-butyl-cis,cis-2,6-dimethyl-, 4-t-butyl-cis,trans-2,6-dimethyl-, 4-t-butyl-cis-2-methyl-, 4-t-butyl-trans-2-methyl-, and 5-t-butyl-cis-2-methylcyclohexyl radicals (12)-(17).The composition of the product mixtures indicates that transfer of axial β-hydrogen atoms occurs more rapidly than does transfer of equatorial β-hydrogen atoms.These results support the hypothesis that homolytic fission of a C-H bond is favoured when it lies chlose to the plane of an adjacent semi-occupied orbital.