909767-34-6

Basic information

• Product Name: C₄₄H₅₈O₂Si₂
• Synonyms: C₄₄H₅₈O₂Si₂
• CAS NO: 909767-34-6
• Molecular Weight: 675.114
• Mol File: 909767-34-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₄₄H₅₈O₂Si₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₄₄H₅₈O₂Si₂(909767-34-6)
• EPA Substance Registry System: C₄₄H₅₈O₂Si₂(909767-34-6)

Safety Data

• Hazardous Substances Data: 909767-34-6(Hazardous Substances Data)

Upstream product

• 676-22-2 (1E,5E,9E)-cyclododeca-1,5,9-triene 
• 60391-93-7 (4E,8E)-dodeca-4,8-dienedial 
• 837382-45-3 trans,trans-5,9-Cyclododecadien-1,2-diol 
• 131392-77-3 (4E,8E)-dodeca-4,8-diene-1,12-diol 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 909767-35-7 cis-4-(tert-butyldiphenylsiloxy)-1-{5-[4-(tert-butyldiphenylsiloxy)-1-hydroxybutyl]tetrahydrofuran-2-yl}butan-1-ol 
• 909767-36-8 Acetic acid (S)-4-(tert-butyl-diphenyl-silanyloxy)-1-{(2S,5R)-5-[(R)-4-(tert-butyl-diphenyl-silanyloxy)-1-hydroxy-butyl]-tetrahydro-furan-2-yl}-butyl ester 

Relevant articles and documents

Total synthesis of cis-solamin: Exploiting the RuO4-catalyzed oxidative cyclization of dienes

An enantioselective total synthesis of cis-solamin has been accomplished using a highly diastereoselective ruthenium tetroxide catalyzed oxidative cyclization as a crucial transformation. Further key steps involved an enzymatic desymmetrization, a TPAP-catalyzed oxidative termini differentiation, and a ruthenium-catalyzed Alder-ene reaction. Thus, the total synthesis of cis-solamin was achieved in 11 steps with an overall yield of 7.5%.