909767-35-7

Basic information

• Product Name: cis-4-(tert-butyldiphenylsiloxy)-1-{5-[4-(tert-butyldiphenylsiloxy)-1-hydroxybutyl]tetrahydrofuran-2-yl}butan-1-ol
• Synonyms: cis-4-(tert-butyldiphenylsiloxy)-1-{5-[4-(tert-butyldiphenylsiloxy)-1-hydroxybutyl]tetrahydrofuran-2-yl}butan-1-ol
• CAS NO: 909767-35-7
• Molecular Weight: 725.128
• Mol File: 909767-35-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: cis-4-(tert-butyldiphenylsiloxy)-1-{5-[4-(tert-butyldiphenylsiloxy)-1-hydroxybutyl]tetrahydrofuran-2-yl}butan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: cis-4-(tert-butyldiphenylsiloxy)-1-{5-[4-(tert-butyldiphenylsiloxy)-1-hydroxybutyl]tetrahydrofuran-2-yl}butan-1-ol(909767-35-7)
• EPA Substance Registry System: cis-4-(tert-butyldiphenylsiloxy)-1-{5-[4-(tert-butyldiphenylsiloxy)-1-hydroxybutyl]tetrahydrofuran-2-yl}butan-1-ol(909767-35-7)

Safety Data

• Hazardous Substances Data: 909767-35-7(Hazardous Substances Data)

Upstream product

• 676-22-2 (1E,5E,9E)-cyclododeca-1,5,9-triene 
• 60391-93-7 (4E,8E)-dodeca-4,8-dienedial 
• 837382-45-3 trans,trans-5,9-Cyclododecadien-1,2-diol 
• 131392-77-3 (4E,8E)-dodeca-4,8-diene-1,12-diol 
• 909767-34-6 C₄₄H₅₈O₂Si₂ 

Downstream Products

• 909767-36-8 Acetic acid (S)-4-(tert-butyl-diphenyl-silanyloxy)-1-{(2S,5R)-5-[(R)-4-(tert-butyl-diphenyl-silanyloxy)-1-hydroxy-butyl]-tetrahydro-furan-2-yl}-butyl ester 

Relevant articles and documents

Multigram synthesis of diastereomerically pure tetrahydrofuran-diols

A highly efficient protocol for the large-scale oxidative cyclization of 1,5-dienes is described. This convenient ruthenium(VIII)-catalyzed (0.2 mol%) cyclization reaction allows the preparation of cis-2,5-disubstituted tetrahydrofurans in high yields (up to 92%) and excellent diastereomeric ratio (>95:5 dr). This simple and reliable method is insensitive to moisture and air and can, therefore, be carried out in an open reaction vessel. Georg Thieme Verlag Stuttgart.