91328-44-8

Basic information

• Product Name: 3-Heptanol, 3-ethyl-5-methyl-
• CAS NO: 91328-44-8
• Molecular Formula: C10H22O
• Molecular Weight: 158.284
• Mol File: 91328-44-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Heptanol, 3-ethyl-5-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Heptanol, 3-ethyl-5-methyl-(91328-44-8)
• EPA Substance Registry System: 3-Heptanol, 3-ethyl-5-methyl-(91328-44-8)

Safety Data

• Hazardous Substances Data: 91328-44-8(Hazardous Substances Data)

Upstream product

• 534-00-9 (+)-1-bromo-2-methylbutane 
• 1192-17-2 2,2-diethyloxirane 

Relevant articles and documents

Substitution Reactions of Secondary Halides and Epoxides with Higher Order, Mixed Organocuprates, R2Cu(CN)Li2: Synthetic, Stereochemical, and Mechanistic Aspects

Higher order cuprates, represented by the general formula R2Cu(CN)Li2, are readily prepared from copper cyanide and 2 equiv of an organolithium.These novel reagents react readily and efficiently with secondary unactivated iodides and bromides affording products of substitution.Likewise, mono-, di-, and trisubstituted epoxides undergo ring opening leading to the corresponding alcohols in excellent yields.The effects of solvent, temperature, gegenion, and variations in ligands are discussed.Replacement of the second equivalent of RLi by CH3Li strongly encouragestransfer of R over CH3 in R(CH3)Cu(CN)Li2 with halides.Use of PhLi as RRLi in place of one RTLi (i.e.RT(Ph)Cu(CN)Li2) is suggested for oxirane cleavage.The stereochemical implications associated with both couplings are also addressed.