91817-69-5

Basic information

• Product Name: Ethanone, 1-(3,4-dimethylphenyl)-, oxime
• Synonyms: 3',4'-dimethylacetophenone oxime;1-(3,4-dimethyl-phenyl)-ethanone oxime;methyl-3,4-dimethylphenylketoxime;Ethanone,1-(3,4-dimethylphenyl)-,oxime;1-(3,4-Dimethyl-phenyl)-aethanon-oxim
• CAS NO: 91817-69-5
• Molecular Formula: C10H13NO
• Molecular Weight: 163.219
• Mol File: 91817-69-5.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-(3,4-dimethylphenyl)-, oxime(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(3,4-dimethylphenyl)-, oxime(91817-69-5)
• EPA Substance Registry System: Ethanone, 1-(3,4-dimethylphenyl)-, oxime(91817-69-5)

Safety Data

• Hazardous Substances Data: 91817-69-5(Hazardous Substances Data)

Upstream product

• 3637-01-2 3,4-dimethylacetophenone 

Downstream Products

• 95-64-7 4-amino-o-xylene 
• 142425-97-6 2-(3,4-dimethylphenyl)-1H-pyrrole 
• 142426-01-5 2-(3,4-Dimethyl-phenyl)-1-vinyl-1H-pyrrole 
• 3637-01-2 3,4-dimethylacetophenone 
• 2198-54-1 N-(3,4-dimethylphenyl)acetamide 
• 1333119-95-1 3',3'-dimethylacetophenone oxime acetate 
• 1333120-01-6 2,6-bis(3,4-dimethylphenyl)-4-phenylpyridine 

Relevant articles and documents

Direct Enamido C(sp2)?H Diphosphorylation Enabled by a PCET-Triggered Double Radical Relay: Access to gem-Bisphosphonates

Herein we report a novel and straightforward protocol for the construction of valuable gem-BPs by means of proton-coupled electron-transfer (PCET)-triggered enamido C(sp2)?H diphosphorylation. This reaction represents a rare example of realizing the challenging double C?P bond formation at a single carbon atom, thus providing facile access to a broad variety of structurally diverse bisphosphonates from simple enamides under silver-mediated conditions. Initial mechanistic studies demonstrated that the diphosphorylation involves two rounds of PCET-initiated radical relay process.

Redox-Neutral Access to Isoquinolinones via Rhodium(III)-Catalyzed Annulations of O-Pivaloyl Oximes with Ketenes

A mild and redox-neutral [4 + 2] annulation of O-pivaloyl oximes with ketenes has been realized for synthesis of quaternary-carbon-stereocenter-containing (QCSC) isoquinolinones, where the N-OPiv not only acts as an oxidizing group but also offers coordination saturation to inhibit protonolysis. The reaction mechanism has been studied by DFT calculations.

Elemental tellurium mediated synthesis of 2-(trifluoromethyl)oxazoles using trifluoroacetic anhydride as reagent

An elemental tellurium mediated synthesis of 2-(trifluoromethyl)oxazoles from the reaction of acetophenone oxime acetates with trifluoroacetic anhydride has been developed. This new tandem cyclization proceeds in good to excellent yields via a SET reduction followed by a 5-endo-trig pathway. Some of the title compounds showed fungicidal and insecticidal activities.