91876-32-3Relevant articles and documents
The Synthesis of D-(6R)- and (6S)-(6-2H1)-Galactose
Ohrui, Hiroshi,Nishida, Yoshihiro,Meguro, Hiroshi
, p. 1049 - 1054 (2007/10/02)
D-(6R)- and (6S) -(6-2H1)-Galactose were regio- and stereospecifically synthesized through photobromination of 1,6-anhydrogalactose derivatives.The (6S)-compound was prepared in a similar manner to our previous synthesis of D-(6S)-(6-2H1)-glucose.The inversion to the (6R)-galacto derivatives was performed via (6S)-(6-2H1)-6-p-toluenesulfonyl-1,2,3,4-di-O-isopropyridene-α-D-galactose.