918831-65-9

Basic information

• Product Name: Benzene, 1-(cyclopropylidenemethyl)-4-(1,1-dimethylethyl)-
• Synonyms: Benzene,1-(cyclopropylidenemethyl)-4-(1,1-dimethylethyl)
• CAS NO: 918831-65-9
• Molecular Formula: C14H18
• Molecular Weight: 186.297
• Mol File: 918831-65-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(cyclopropylidenemethyl)-4-(1,1-dimethylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(cyclopropylidenemethyl)-4-(1,1-dimethylethyl)-(918831-65-9)
• EPA Substance Registry System: Benzene, 1-(cyclopropylidenemethyl)-4-(1,1-dimethylethyl)-(918831-65-9)

Safety Data

• Hazardous Substances Data: 918831-65-9(Hazardous Substances Data)

Upstream product

• 939-97-9 4-tert-Butylbenzaldehyde 
• 3607-17-8 3-bromopropyltriphenylphosphonium bromide 
• 14114-05-7 cyclopropyltriphenylphosphonium bromide 

Relevant articles and documents

Nickel-Catalyzed Favorskii-Type Rearrangement of Cyclobutanone Oxime Esters to Cyclopropanecarbonitriles

A nickel-catalyzed base-promoted rearrangement of cyclobutanone oxime esters to cyclopropanecarbonitriles was developed. The ring opening of cyclobutanone oxime esters occurs at the sterically less hindered side. A base-promoted nickelacyclobutane intermediate, formed in situ, is assumed to be involved in the formation of the product.

A new protocol for nickel-catalysed regio- and stereoselective hydrocyanation of allenes

Regio- and stereoselective hydrocyanation under nickel catalysis is described. This report shows that allenyl C-C double bonds are discriminated and converted to the corresponding carbonitriles as a single product. The key functionalities for achieving high regio- and stereocontrol are aryl and cyclopropyl groups in the substrates. This journal is