92548-93-1

Basic information

• Product Name: 4-benzylphenyl acetate
• CAS NO: 92548-93-1
• Molecular Formula: C₁₅H₁₄O₂
• Molecular Weight: 226.2705
• Mol File: 92548-93-1.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 338.2°C at 760 mmHg
• Flash Point: 117.2°C
• Density: 1.095g/cm³
• Vapor Pressure: 9.96E-05mmHg at 25°C
• Refractive Index: 1.561
• CAS DataBase Reference: 4-benzylphenyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-benzylphenyl acetate(92548-93-1)
• EPA Substance Registry System: 4-benzylphenyl acetate(92548-93-1)

Safety Data

• Hazardous Substances Data: 92548-93-1(Hazardous Substances Data)

Upstream product

• 101-53-1 p-benzylphenol 
• 108-24-7 acetic anhydride 
• 64-19-7 acetic acid 
• 75-36-5 acetyl chloride 
• 720-44-5 1-(4-methoxyphenyl)-1-phenylmethanol 
• 1137-42-4 4-Hydroxybenzophenone 
• 100-44-7 benzyl chloride 
• 122-79-2 Phenyl acetate 
• 100-58-3 phenylmagnesium bromide 
• 123-08-0 4-hydroxy-benzaldehyde 
• 833-39-6 4-hydroxy-benzhydrol 
• 108-05-4 vinyl acetate 

Downstream Products

• 833-39-6 4-hydroxy-benzhydrol 
• 131060-21-4 2-ethyl-4-benzyl-phenol 
• 101-53-1 p-benzylphenol 
• 64-19-7 acetic acid 
• 61300-15-0 1-(5-benzyl-2-hydroxyphenyl)ethanone 
• 92434-59-8 4-Acetoxy-benzhydrylbromid 
• 13031-44-2 4-acetoxybenzophenone 

Relevant articles and documents

The first vinyl acetate mediated organocatalytic transesterification of phenols: A step towards sustainability

The present report outlines our efforts toward a simple yet elegant protocol for O-acylation of a wide variety of phenols. This highly enabling and solventless method relies on vinyl acetate as an innocuous acyl donor and DABCO as an organocatalyst. Operational simplicity, excellent yields, higher and faster conversion rates without excess reagents, a simple workup and essentially no need of columns are some of the salient features of the reported protocol.

Iron-doped single-walled carbon nanotubes as new heterogeneous and highly efficient catalyst for acylation of alcohols, phenols, carboxylic acids and amines under solvent-free conditions

Iron-doped single-walled carbon nanotubes (Fe/SWCNTs) represent an efficient and new heterogeneous reusable catalyst for the acylation of a variety of alcohols, phenols, carboxylic acids and amines with acid chlorides or acid anhydrides under solvent-free conditions. The reactions of various primary, secondary, tertiary, and benzylic alcohols, diols, phenols, as well as aromatic and aliphatic amines give acylated adducts in good to excellent yields.

A metal-free catalytic system for the oxidation of benzylic methylenes and primary amines under solvent-free conditions

Iodine-pyridine-tert-butylhydroperoxide is developed as a green and efficient catalytic system for the oxidation of benzylic methylenes to ketones and primary amines to nitriles. The reaction conditions are quite mild and environmentally benign, no transition metals, organic solvents or hazard reagents being needed. The oxidation of benzylic methylenes gave the corresponding ketones in excellent yields with complete chemoselectivity, while the oxidation of primary amines was complete in several minutes, affording various nitriles in moderate to good yields.