92560-92-4

Basic information

• Product Name: Benzoic acid, 4-methoxy-, 1-methyl-2-oxo-2-phenylethyl ester
• CAS NO: 92560-92-4
• Molecular Formula: C17H16O4
• Molecular Weight: 284.312
• Mol File: 92560-92-4.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 4-methoxy-, 1-methyl-2-oxo-2-phenylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-methoxy-, 1-methyl-2-oxo-2-phenylethyl ester(92560-92-4)
• EPA Substance Registry System: Benzoic acid, 4-methoxy-, 1-methyl-2-oxo-2-phenylethyl ester(92560-92-4)

Safety Data

• Hazardous Substances Data: 92560-92-4(Hazardous Substances Data)

Upstream product

• 536-45-8 sodium anisate 
• 2114-00-3 2-bromo-1-phenyl-1-propanone 
• 637-69-4 4-Methoxystyrene 
• 93-55-0 1-phenyl-propan-1-one 
• 768-60-5 4-methoxyphenylacetylen 
• 103-65-1 phenylpropane 
• 100-09-4 4-methoxybenzoic acid 
• 93-54-9 1-Phenyl-1-propanol 
• 104-93-8 p-methylanizole 
• 637-50-3 1-phenylpropene 

Downstream Products

• 92560-96-8 4-(5-Methyl-4-phenyl-oxazol-2-yl)-phenol 
• 92560-98-0 2-Methyl-2-[4-(5-methyl-4-phenyl-oxazol-2-yl)-phenoxy]-propionic acid ethyl ester 
• 92561-04-1 2-Methyl-2-[4-(5-methyl-4-phenyl-oxazol-2-yl)-phenoxy]-propionic acid 
• 92560-97-9 [4-(5-Methyl-4-phenyl-oxazol-2-yl)-phenoxy]-acetic acid ethyl ester 
• 92561-03-0 [4-(5-Methyl-4-phenyl-oxazol-2-yl)-phenoxy]-acetic acid 

Relevant articles and documents

Copper-catalyzed α-C-H acyloxylation of carbonyl compounds with terminal alkynes

Herein, a copper/TBHP catalyst system for the α-C-H acyloxylation of carbonyl compounds is developed using terminal alkynes as the acyloxy source. A variety of carbonyl compounds and terminal alkynes are tolerated in this reaction. In addition, its possible mechanism is proposed.

Method for preparing alpha-acyloxy ketone compound from terminal alkyne compounds

The invention provides a method for efficiently synthesizing an alpha-acyloxy ketone compound containing different substitute functional groups. According to the method, acetylacetone copper is taken as a reaction catalyst, t-butylhydroperoxide is taken as an antioxidant, ketone compounds and terminal alkyne compounds are taken as reaction substrates, and an organic solvent is added into a reaction system. The method has the advantages that the catalyst is cheap and easily available; reaction conditions are mild, safe and reliable; and the productivity of an obtained target product is relatively high. According to the method, the problem that a traditional alpha-acyloxylation reaction system is single is solved, and a novel acyloxylation reagent is provided; and the method has good industrial application prospects.

NBS/DBU mediated one-pot synthesis of α-acyloxyketones from benzylic secondary alcohols and carboxylic acids

A simple and efficient one-pot NBS/DBU-mediated method has been developed for the synthesis of α-acyloxyketones from various benzylic secondary alcohols and carboxylic acids. Through this methodology, a series of α-acyloxyketones could be obtained in good to excellent yields under mild conditions. Importantly, this new reaction avoids the direct usage of toxic metal catalysts or potentially dangerous peroxide oxidants.