931094-47-2

Basic information

• Product Name: (E)-(R)-3-Oxo-7-phenyl-5-trimethylsilanyloxy-hept-6-enoic acid methyl ester
• Synonyms: (E)-(R)-3-Oxo-7-phenyl-5-trimethylsilanyloxy-hept-6-enoic acid methyl ester
• CAS NO: 931094-47-2
• Molecular Weight: 320.461
• Mol File: 931094-47-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-(R)-3-Oxo-7-phenyl-5-trimethylsilanyloxy-hept-6-enoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(R)-3-Oxo-7-phenyl-5-trimethylsilanyloxy-hept-6-enoic acid methyl ester(931094-47-2)
• EPA Substance Registry System: (E)-(R)-3-Oxo-7-phenyl-5-trimethylsilanyloxy-hept-6-enoic acid methyl ester(931094-47-2)

Safety Data

• Hazardous Substances Data: 931094-47-2(Hazardous Substances Data)

Upstream product

• 14371-10-9 (E)-3-phenylpropenal 
• 81114-98-9 Chan's diene 

Downstream Products

• 500-64-1 Kavain 
• 356793-34-5 (E)-(R)-5-Hydroxy-3-oxo-7-phenyl-hept-6-enoic acid methyl ester 

Relevant articles and documents

A new procedure for the enantioselective vinylogous aldol reaction of Chan's diene

Chiral δ-hydroxy-β-ketoesters are easily available through the enantioselective vinylogous aldol reaction of Chan's diene promoted by a SiCl4/chiral phosphoramide catalytic system. The procedure is conveniently exploited for a very rapid approach to (+)-kavain, a natural bio-active α-pyrone compound.