935521-44-1

Basic information

• Product Name: 1-[2-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-5,5-dimethyl-hept-6-en-1-yn-3-one
• Synonyms: 1-[2-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-5,5-dimethyl-hept-6-en-1-yn-3-one
• CAS NO: 935521-44-1
• Molecular Weight: 356.58
• Mol File: 935521-44-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-[2-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-5,5-dimethyl-hept-6-en-1-yn-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[2-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-5,5-dimethyl-hept-6-en-1-yn-3-one(935521-44-1)
• EPA Substance Registry System: 1-[2-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-5,5-dimethyl-hept-6-en-1-yn-3-one(935521-44-1)

Safety Data

• Hazardous Substances Data: 935521-44-1(Hazardous Substances Data)

Upstream product

• 63721-05-1 methyl 3,3-dimethyl-4-penteneoate 
• 935521-43-0 3,3-dimethyl-pent-4-enoic acid methoxy-methyl-amide 
• 173074-01-6 1-<<(tert-butyldimethylsilyl)oxy>methyl>-2-ethynylbenzene 
• 88819-78-7 3,3-dimethylpent-4-enoic acid chloride 
• 7796-73-8 3,3-dimethylpent-4-enoic acid 

Relevant articles and documents

Synthesis of alkylidenephthalans through fluoride-induced cyclization of electron-deficient 2-siloxymethylphenylacetylene derivatives

Fluoride-based deprotection of silylated 2-alkynylbenzyl alcohol derivatives featuring carbonyl-substituted alkynes results in the direct synthesis of alkylidenephthalan vinylogous esters. The reaction is selective for the Z alkylidenephthalans in a therm