93877-01-1

Basic information

• Product Name: Cyclohexanone, 2-[1,1'-biphenyl]-4-yl-
• CAS NO: 93877-01-1
• Molecular Formula: C18H18O
• Molecular Weight: 250.34
• Mol File: 93877-01-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 2-[1,1'-biphenyl]-4-yl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 2-[1,1'-biphenyl]-4-yl-(93877-01-1)
• EPA Substance Registry System: Cyclohexanone, 2-[1,1'-biphenyl]-4-yl-(93877-01-1)

Safety Data

• Hazardous Substances Data: 93877-01-1(Hazardous Substances Data)

Upstream product

• 92-66-0 4-bromo-1,1'-biphenyl 
• 822-87-7 2-Chlorocyclohexanone 
• 5122-94-1 4-biphenylboronic acid 
• 16885-20-4 4-(1',3'-dithian-2'-yl)but-1-ene 
• 2567-29-5 p-phenylbenzyl bromide 
• 838826-61-2 1-biphenyl-4-yl-hex-5-en-2-one 
• 93902-63-7 2-(4-Xenyl)-cyclohexanol 
• 2562-37-0 1-nitrocyclohexene 
• 71-43-2 benzene 

Downstream Products

• 96468-27-8 2-(4-Xenyl)-1-(3-xenyl)-cyclohexanol-⁽¹⁾ 
• 95622-40-5 1-Phenyl-2-(4-xenyl)-cyclohexanol 
• 5366-53-0 6-(4'-Biphenylyl)-6-keto-hexanoic acid 
• 1402080-69-6 (-)-(S)-2-([1,1'-biphenyl]-4-yl)cyclohexanone 
• 1402080-79-8 (+)-(R)-3-([1,1'-biphenyl]-4-yl)oxepan-2-one 
• 1402080-88-9 7-([1,1'-biphenyl]-4-yl)oxepan-2-one 
• 5660-40-2 Quiniqui<3.2.4>phenyl 
• 5660-43-5 4,4''-diphenyl-o-terphenyl 
• 1165-58-8 o,p-quaterphenyl 
• 107526-97-6 2,4'-Di-(4-xenyl)-biphenyl 
• 96468-28-9 1,2-Di-(4-Xenyl)-cyclohexanol-⁽¹⁾ 

Relevant articles and documents

Selective C-C Bond Cleavage of Cycloalkanones by NaNO2/HCl

A novel selective fragmentation of cycloalkanones by NaNO2/HCl has been established. The C-C bond cleavage reaction proceeds smoothly under mild conditions, selectively affording versatile keto acids or oxime acids. The methodology can streamline the synthesis of valuable chiral molecules and isocoumarins from readily available feedstocks.

Reactions of O,O-Diprotonated Nitro Olefins with Benzenes. Formations of Phenylacetones, 4H-1,2-Benzoxazines and Biarylacetone Oximes

O,O-Diprotonated nitro olefins undergo three alternative electrophilic reactions which yield α-phenylacetones, 4H-1,2-benzoxazines and biphenylacetone oximes depending on the reaction conditions (temperature and time) and aromatic substrates.Although these reactions are seemingly divergent, a common intermediate of a phenylated protonated aci-nitro species, derived from the dication, is postulated to be involved in the reactions.Furthermore, the formation of benzoxazines and biphenylacetone oximes can be interpreted in terms of participation of novel chemical species with phenylethylene dication character derived from the common intermediate.