94225-32-8

Basic information

• Product Name: Ethanone, 2-(2-chloro-1-hydroxycyclohexyl)-1-phenyl-, cis-
• CAS NO: 94225-32-8
• Molecular Formula: C14H17ClO2
• Molecular Weight: 252.741
• Mol File: 94225-32-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Ethanone, 2-(2-chloro-1-hydroxycyclohexyl)-1-phenyl-, cis-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 2-(2-chloro-1-hydroxycyclohexyl)-1-phenyl-, cis-(94225-32-8)
• EPA Substance Registry System: Ethanone, 2-(2-chloro-1-hydroxycyclohexyl)-1-phenyl-, cis-(94225-32-8)

Safety Data

• Hazardous Substances Data: 94225-32-8(Hazardous Substances Data)

Upstream product

• 17851-98-8 1-phenyl-1-(tributylstannyloxy)ethene 
• 822-87-7 2-Chlorocyclohexanone 
• 25445-76-5 acetophenone N-ethoxycarbonylhydrazone 

Relevant articles and documents

Catalytic Effect of Five-Coordinate Organotin Bromide or Tetraphenylstibonium Bromide on the Chemo- and Stereoselective Addition of Tin Enolate to α-Halo Ketone

Two types of catalysts, five-coordinate organotin bromides and tetraphenylstibonium bromide, similarly promoted the selective addition of tin enolates to the carbonyl moiety in α-halo ketones.The reaction with 2-chlorocyclohexanones and the enolates gave

REACTION OF α-CHLOROKETONES WITH 1,4-DIANION OF ACETOPHENONE N-ETHOXYCARBONYLHYDRAZONE

1,4-Dianion of acetophenone N-ethoxycarbonylhydrazone (2) reacts with α-chloroketones such as phenacyl chloride, 1-chloroacetone, 3-chloro-2-butanone, and 1,3-dichloroacetone to give pyrazoline derivatives in good yields.In the reactions of 2-chlorocyclohexanone and 3-chloro-2-norbornanone with 2, cis-chlorohydrin and exo-chlorohydrin were selectively obtained, respectively.