946088-68-2

Basic information

• Product Name: benzyl 2-methylaziridine-1-carboxylate
• Synonyms: benzyl 2-methylaziridine-1-carboxylate
• CAS NO: 946088-68-2
• Molecular Weight: 191.23
• Mol File: 946088-68-2.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 289.1±19.0 °C(Predicted)
• Density: 1.176±0.06 g/cm3(Predicted)
• CAS DataBase Reference: benzyl 2-methylaziridine-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl 2-methylaziridine-1-carboxylate(946088-68-2)
• EPA Substance Registry System: benzyl 2-methylaziridine-1-carboxylate(946088-68-2)

Safety Data

• Hazardous Substances Data: 946088-68-2(Hazardous Substances Data)

Upstream product

• 5532-86-5 benzyl cyanoformate 
• 52340-20-2 (S)-2-methylaziridine 
• 501-53-1 benzyl chloroformate 
• 6429-44-3 (S)-(-)-N-(benzyloxycarbonyl)alaninol 

Downstream Products

• 881206-91-3 (S)-benzyl 1-(3-acetylphenyl)propan-2-ylcarbamate 
• 946088-72-8 C₁₉H₂₃NO₃ 
• 946088-73-9 Benzyl (S)-1-(3-((R)-1-hydroxyethyl)phenyl)propan-2-ylcarbamate 
• 1057086-31-3 benzyl (S)-1-(3-((S)-1-azidoethyl)phenyl)propan-2-ylcarbamate 
• 881207-02-9 Benzyl (S)-1-(3-((R)-1-aminoethyl)phenyl)propan-2-ylcarbamate 
• 1057086-30-2 benzyl (S)-1-(3-((S)-1-aminoethyl)phenyl)propan-2-ylcarbamate 
• 913722-72-2 benzyl (S)-1-(3-((S)-1-N-Boc-aminoethyl)phenyl)propan-2-ylcarbamate 
• 946088-74-0 C₁₉H₂₂N₂O₃ 
• 946088-61-5 C₃₁H₃₁N₂O₃P 
• 1057253-68-5 (S)-benzyl 1-(3-(2-hydroxypropan-2-yl)phenyl)propan-2-ylcarbamate 
• 1057253-65-2 (S)-benzyl 1-(3-(2-azidopropan-2-yl)phenyl)propan-2-ylcarbamate 
• 1447347-67-2 C₁₄H₁₉NO₃ 
• 52340-20-2 (S)-2-methylaziridine 

Relevant articles and documents

Scalable synthesis of N -acylaziridines from N -tosylaziridines

N-Acylaziridines are important starting materials for the synthesis of chiral amine derivatives. The traditional methods for producing these activated aziridines have significant drawbacks. The gram scale synthesis of N-acylaziridines by deprotection of N

Comparative approaches toward diamines containing spatially separated homobenzylic and benzylic nitrogen stereocenters

Several synthetic strategies to diamines 1-3 are described. The optimum approach via opening of aziridine afforded 1-3 in 29-60% yield over 3-5 steps. A study on formation of the benzylic stereocenter using Toste's rhenium-catalyzed asymmetric reduction of phosphinyl ketimines was also evaluated and afforded 15 in 92% de.