947241-01-2

Basic information

• Product Name: benzyl (5-cyclohexylidene-2,2-diphenyl-4-pentenyl)-carbamate
• Synonyms: benzyl (5-cyclohexylidene-2,2-diphenyl-4-pentenyl)-carbamate
• CAS NO: 947241-01-2
• Molecular Weight: 451.609
• Mol File: 947241-01-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: benzyl (5-cyclohexylidene-2,2-diphenyl-4-pentenyl)-carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl (5-cyclohexylidene-2,2-diphenyl-4-pentenyl)-carbamate(947241-01-2)
• EPA Substance Registry System: benzyl (5-cyclohexylidene-2,2-diphenyl-4-pentenyl)-carbamate(947241-01-2)

Safety Data

• Hazardous Substances Data: 947241-01-2(Hazardous Substances Data)

Upstream product

• 119053-78-0 3-[1-((tetrahydro-2H-pyran-2-yl)oxy)cyclohexyl]prop-2-yn-1-ol 
• 78-27-3 1-Ethynylcyclohexan-1-ol 
• 56037-79-7 3-cyclohexylideneprop-2-en-1-ol 
• 42969-66-4 2-(1-ethynyl-cyclohexyloxy)-tetrahydro-pyran 
• 947241-24-9 5-cyclohexylidene-2,2-diphenyl-4-pentenenitrile 
• 501-53-1 benzyl chloroformate 

Relevant articles and documents

Gold(I)-catalyzed enantioselective hydroamination of N-allenyl carbamates

Treatment of the W-4,5-hexadienyl carbamate 2a with a catalytic 1:2 mixture of [(S)-1]Au2Cl2 [(S)-1 = (S)-3,5-t-Bu-4-MeO-MeOBIPHEP] and AgClO4 in m-xylene at -40°C for 24 h led to isolation of 2-vinylpyrrolidine 3a in 97% yield with 81% ee. Gold(I)-catalyzed enantioselective hydroamination was effective for a number of carbamate groups and tolerated terminal disubstitutution of the allenyl moiety.