56037-79-7Relevant articles and documents
Borylative Cyclization of 1,6-Allenynes Driven by BCl3
Jiang, Ling,Kong, Xiangtao,Liu, Mingzhu,Niu, Congcong,Sun, Xiangkun,Yang, Chun-Hua,Yang, Zhantao,Zhang, Zhiwei,Zheng, Fangjie
supporting information, p. 8050 - 8055 (2021/10/25)
A metal-free intramolecular borylative cyclization of 1,6-allenynes driven by BCl3 was developed. This method provides a general and practical strategy to construct valuable pyrrolidines containing all-carbon quaternary centers or 3,5-dihydroazepine deriv
Regioselective Rh-Catalyzed Hydroformylation of 1,1,3-Trisubstituted Allenes Using BisDiazaPhos Ligand
Eshon, Josephine,Landis, Clark R.,Schomaker, Jennifer M.
, p. 9270 - 9278 (2017/09/22)
The efficient hydroformylation of 1,1,3-trisubstituted allenes is accomplished with low loadings of a Rh catalyst supported by a BisDiazaPhos (BDP) ligand. The ligand identity is key to achieving high regioselectivity, while the mild reaction conditions m
Asymmetric gold-catalyzed lactonizations in water at room temperature
Handa, Sachin,Lippincott, Daniel J.,Aue, Donald H.,Lipshutz, Bruce H.
, p. 10658 - 10662 (2015/05/13)
Asymmetric gold-catalyzed hydrocarboxylations are reported that show broad substrate scope. The hydrophobic effect associated with in situ-formed aqueous nanomicelles gives good to excellent ee's of product lactones. In-flask product isolation, along with
