947265-19-2

Basic information

• Product Name: Oc₂Sn(N-nitroso-N-phenylhydroxylaminate)2
• CAS NO: 947265-19-2
• Molecular Weight: 619.392
• Mol File: 947265-19-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Oc₂Sn(N-nitroso-N-phenylhydroxylaminate)2(CAS DataBase Reference)
• NIST Chemistry Reference: Oc₂Sn(N-nitroso-N-phenylhydroxylaminate)2(947265-19-2)
• EPA Substance Registry System: Oc₂Sn(N-nitroso-N-phenylhydroxylaminate)2(947265-19-2)

Safety Data

• Hazardous Substances Data: 947265-19-2(Hazardous Substances Data)

Upstream product

• 870-08-6 dioctyltin(IV) oxide 
• 3542-36-7 di-n-octyltin dichloride 

Relevant articles and documents

Preparation and structural studies on diorganotin(IV) complexes of N-nitroso-N-phenylhydroxylaminates

Diorganotin(IV)-complexes of the N-nitroso-N-phenylhydroxylaminates (hereinafter cupf), Et2Sn(cupf)2 (1), Bu2Sn(cupf)2 (2), {[Bu2Sn(cupf)]2O}2 (3), t-Bu2Sn(cupf)2 (4) and Oc2Sn(cupf)2 (5, 6) were prepared and characterised by FT-IR and M?ssbauer spectroscopic measurements. The binding modes of the ligand were identified by FT-IR spectroscopy, and it was found that the ligand is coordinated in chelating or bridging mode to the organotin(IV) center. The 119Sn M?ssbauer and FT-IR studies support the formation of trans-Oh (1-6) structures. The X-ray diffraction analysis of 4 revealed that the tin centre is in a skew-trapezoidal geometry defined by four donors derived from the cupferronato ligands and two carbon atoms from the tin-bound tbutyl substituents. The 119Sn NMR investigations indicate that in solution 4 retains its hexacoordinated nature.