948-15-2

Basic information

• Product Name: {exo-bicyclo[2.2.1]heptan-2-yl}(phenyl)ketone
• Synonyms: {exo-bicyclo[2.2.1]heptan-2-yl}(phenyl)ketone
• CAS NO: 948-15-2
• Molecular Weight: 200.28
• Mol File: 948-15-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: {exo-bicyclo[2.2.1]heptan-2-yl}(phenyl)ketone(CAS DataBase Reference)
• NIST Chemistry Reference: {exo-bicyclo[2.2.1]heptan-2-yl}(phenyl)ketone(948-15-2)
• EPA Substance Registry System: {exo-bicyclo[2.2.1]heptan-2-yl}(phenyl)ketone(948-15-2)

Safety Data

• Hazardous Substances Data: 948-15-2(Hazardous Substances Data)

Upstream product

• 4885-02-3 Dichloromethyl methyl ether 
• 109529-25-1 (exo-2-norbornyl)(phenyl)(isopropyl)borane 
• 934-28-1 bicyclo(2.2.1)heptane-2-endo-carboxylic acid 
• 498-66-8 norborn-2-ene 
• 100-52-7 benzaldehyde 
• 591-51-5 phenyllithium 
• 98-88-4 benzoyl chloride 
• 6343-27-7 1-benzoylpyrrolidine-2,5-dione 
• 279-23-2 norbornane 
• 498-66-8 norbornene 
• 934-29-2 acide bicyclo<2.2.1>heptane carboxylique-2 exo 
• 934-27-0 exo-2-norbornanecarbonyl chloride 
• 71-43-2 benzene 
• 768-03-6 Phenyl vinyl ketone 

Downstream Products

• 13305-44-7 (1S,2S,4R)-Bicyclo[2.2.1]hept-2-yl-phenyl-methanol 
• 74998-87-1 Methanesulfonic acid (1R,2R,4S)-bicyclo[2.2.1]hept-2-yl-phenyl-methyl ester 
• 74998-81-5 Acetic acid (S)-(1R,2R,4S)-bicyclo[2.2.1]hept-2-yl-phenyl-methyl ester 
• 74998-80-4 Acetic acid (R)-(1R,2R,4S)-bicyclo[2.2.1]hept-2-yl-phenyl-methyl ester 

Relevant articles and documents

Double acylation of alkenes with acylchromates promoted by cationic Pd(II) complex

Double acylation of alkenes such as norbornene and vinyl-silane proceeds by the use of acylchromate complexes and a cationic Pd(II) complex. When two different acylchromates are added successively to a mixture of alkene and the Pd complex, unsymmetrical diketones are obtained almost selectively.

Palladium-catalyzed formal hydroacylation of allenes employing acid chlorides and hydrosilanes

The palladium-catalyzed formal hydroacylation of allenes employing acid chlorides and hydrosilanes has been achieved. The reactions proceed with commercially available Pd(OAc)2 as a catalyst and HSi(iPr) 3 as a reducing reagent, giving the corresponding α,β-unsaturated ketones regio- and stereoselectively.