954114-56-8Relevant articles and documents
Ruthenium-Catalyzed Oxidative Transformation of Alkenes to α-Ketols with Peracetic Acid. Simple Synthesis of Cortisone Acetate
Murahashi, Shun-Ichi,Saito, Takao,Hanaoka, Hidenori,Murakami, Yoshihide,Naota, Takeshi,et al.
, p. 2929 - 2930 (1993)
The reactions of alkenes with peracetic acid in the presence of RuCl3 catalyst gave the corresponding α-ketols, which are important building units for synthesis of biological active compounds, such as cortisone acetate.
Straightforward synthesis of α,β-epoxysilanes from terminal epoxides by lithium 2,2,6,6-tetramethylpiperidide-mediated deprotonation-in situ silylation
Hodgson, David M.,Reynolds, Nigel J.,Coote, Steven J.
, p. 7895 - 7897 (2007/10/03)
Lithiation-in situ silylation of simple terminal epoxides using lithium 2,2,6,6-tetramethylpiperidide in combination with trimethylsilyl chloride provides a direct and experimentally convenient process for the synthesis of trans-α,β-epoxysilanes.
