96746-56-4Relevant articles and documents
The CF3CH2O- adducts of α-nitro-β-(2,2,2-trifluoroethoxy)stilbene and β-methoxy-α-nitrostilbene, and the MeO- adduct of β-methoxy-α-nitrostilbene. Kinetics of competition between protonation and acid catalyzed a
Bernasconi, Claude F.,Schuck, David F.,Ketner, Rodney J.,Eventova, Irina,Rappoport, Zvi
, p. 2719 - 2725 (2007/10/02)
The reaction of aqueous acids with the CF3CH2O- adduct, Ph(OCH2CF3)2CC(Ph)=NO2-, of α-nitro-β-(2,2,2-trifluoroethoxy)stilbene leads virtually exclusively to the corres
Kinetic analysis of elementary steps in nucleophilic vinylic substitution reactions of α-nitro-β-X-stilbenes (X = OCH2CF3, OCH3, NO2) with various nucleophiles.
Bernasconi, Claude F.,Schuck, David F.,Ketner, Rodney J.,Weiss, Minda,Rappoport, Zvi
, p. 11764 - 11774 (2007/10/02)
Rate constants of elementary steps in the addition-elimination mechanism of nucleophilic vinylic substitutions (SNV) were determined by studying the following reactions in 50% Me2SO-50% water at 20 °C: (1) α-nitro-β-(2,2,2-trifluoroethoxy)stilb
Kinetics of reactions of hydroxide ion and water with β-X-substituted α-nitrostilbenes (X = Cl, I, SEt, OMe, SCH2CH2OH) in 50% Me2SO-50% water. Search for the intermediate in nucleophilic vinylic substitution
Bernasconi, Claude F.,Fassberg, Julianne,Killion Jr., Robert B.,Schuck, David F.,Rappoport, Zvi
, p. 4937 - 4946 (2007/10/02)
The hydrolysis of Ph(LG)C=Cph(NO2) (4-LG, Lg = Cl, I, Set, Ome) in basic solution yields the anion of 1,2-diphenyl-2-nitroethanone, PhC(=O)C(=NO2-)Ph (8-), by the addition-elimanation mechanism of nucleophilic v