96845-35-1

Basic information

• Product Name: (R)-3-((1R,3aR,4S,7aR)-4-Benzyloxy-7a-methyl-octahydro-inden-1-yl)-butyraldehyde
• Synonyms: (R)-3-((1R,3aR,4S,7aR)-4-Benzyloxy-7a-methyl-octahydro-inden-1-yl)-butyraldehyde
• CAS NO: 96845-35-1
• Molecular Weight: 314.468
• Mol File: 96845-35-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (R)-3-((1R,3aR,4S,7aR)-4-Benzyloxy-7a-methyl-octahydro-inden-1-yl)-butyraldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-3-((1R,3aR,4S,7aR)-4-Benzyloxy-7a-methyl-octahydro-inden-1-yl)-butyraldehyde(96845-35-1)
• EPA Substance Registry System: (R)-3-((1R,3aR,4S,7aR)-4-Benzyloxy-7a-methyl-octahydro-inden-1-yl)-butyraldehyde(96845-35-1)

Safety Data

• Hazardous Substances Data: 96845-35-1(Hazardous Substances Data)

Upstream product

• 96845-34-0 (R)-3-((1R,3aR,4S,7aR)-4-Benzyloxy-7a-methyl-octahydro-inden-1-yl)-butyronitrile 
• 146434-14-2 <1R-<1α(R^*),3aβ,4α,7aα>>-4-(benzyloxy)octahydro-γ,7a-dimethyl-1H-indene-1-propanol 
• 131336-04-4 (2R,3R)-3-<(1R)-2-(methoxycarbonyl)-1-methylethyl>-2-methylcyclopentanone 
• 146433-98-9 (2R,3R)-3-((R)-3-Hydroxy-1-methyl-propyl)-2-methyl-cyclopentanone 
• 131336-02-2 (1S,2R,3S,4R,5R)-3,5-Dimethyl-6-oxo-bicyclo[2.2.1]heptane-2-carboxylic acid 
• 131336-03-3 methyl (1S,2R,3S,4R,5R)-3,5-dimethyl-6-oxobicyclo<2.2.1>heptane-2-carboxylate 
• 146434-07-3 (1R,7aR)-1-((R)-3-Hydroxy-1-methyl-propyl)-7a-methyl-1,2,5,6,7,7a-hexahydro-inden-4-one 
• 146433-99-0 (2R,3R)-3-<(1R)-3-<(tert-butyldiphenylsilyl)oxy>-1-methylpropyl>-2-methylcyclopentanone 
• 146434-11-9 <1R-(1α,3aβ,7aα)>-1-<(1R)-3-<(tert-butyldiphenylsilyl)oxy>-1-methylpropyl>octahydro-7a-methyl-4H-inden-4-one 
• 146434-09-5 <1R-(1α,4β,7aα)>-1-<(1R)-3-<(tert-butyldiphenylsilyl)oxy>-1-methylpropyl>-2,4,5,6,7,7a-hexahydro-7a-methyl-1H-inden-4-ol 
• 146434-01-7 <1R-(1α,5α,7aα)>-1-<(1R)-3-<(tert-butyldiphenylsilyl)oxy>-1-methylpropyl>-2,3,5,6,7,7a-hexahydro-7a-methyl-1H-inden-5-ol 
• 146434-00-6 <1R-(1α,7aα)>-1-<(1R)-3-<(tert-butyldiphenylsilyl)oxy>-1-methylpropyl>-1,2,3,6,7,7a-hexahydro-7a-methyl-5H-inden-5-one 
• 146434-08-4 <1R-(1α,7aα)>-1-<(1R)-3-<(tert-butyldiphenylsilyl)oxy>-1-methylpropyl>-1,2,5,6,7,7a-hexahydro-7a-methyl-4H-inden-4-one 
• 146434-05-1 <1R-(1α,5α,7aα)>-1-<(1R)-3-<(tert-butyldiphenylsilyl)oxy>-1-methylpropyl>-2,3,5,6,7,7a-hexahydro-4-methoxy-7a-methyl-1H-inden-5-ol 

Downstream Products

• 146434-15-3 <1R-<1α(R^*),3aβ,4α,7aα>>-4-(benzyloxy)octahydro-δ,7a-dimethyl-1H-indene-1-pentenoic acid ethyl ester 
• 96964-11-3 (4S,6S)-2-[(R)-2-((1R,3aR,4S,7aR)-4-Benzyloxy-7a-methyl-octahydro-inden-1-yl)-propyl]-4,6-dimethyl-[1,3]dioxane 
• 96845-42-0 (8S,23S,25R)-de-A,B-8-(benzyloxy)cholestan-23,25,26-triol 
• 66774-84-3 de-A,B-25-hydroxycholestan-8β-ol 
• 70550-73-1 (1R,3aR,7aR)-1-[(2R)-6-hydroxy-6-methylhept-2-yl]-7a-methyloctahydroinden-4-one 
• 96845-36-2 (2S,4R)-4-{(S)-1-[(R)-2-((1R,3aR,4S,7aR)-4-Benzyloxy-7a-methyl-octahydro-inden-1-yl)-propyl]-3-methyl-but-3-enyloxy}-pentan-2-ol 
• 96845-37-3 (R)-4-{(S)-1-[(R)-2-((1R,3aR,4S,7aR)-4-Benzyloxy-7a-methyl-octahydro-inden-1-yl)-propyl]-3-methyl-but-3-enyloxy}-pentan-2-one 

Relevant articles and documents

Stereoselective Synthesis of Cyclopentanones by Reductive Cleavage of 6-Oxonorbornane-2-carboxylates and Its Application to the Synthesis of 1α,25-Dihydroxyvitamin D3 CD Ring

A novel chiral synthesis of the CD-ring 2 of 1α,25-dihydroxyvitamin D3 (1a) is described.The optically active D-ring keto ester 3c was prepared by reductive cleavage of 6-oxonorbornane-2-carboxylate 4c with lithium naphthalenide. 1,2-Transposit