97060-59-8

Basic information

• Product Name: (E,2'RS,3'RS)- and (E,2'RS,3'SR)-1-(3'-(4-bromophenyl)-3'-hydroxy-2'-methyl-1'-oxo-4'-hexenyl)pyrrolidine
• Synonyms: (E,2'RS,3'RS)- and (E,2'RS,3'SR)-1-(3'-(4-bromophenyl)-3'-hydroxy-2'-methyl-1'-oxo-4'-hexenyl)pyrrolidine
• CAS NO: 97060-59-8
• Molecular Weight: 352.271
• Mol File: 97060-59-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (E,2'RS,3'RS)- and (E,2'RS,3'SR)-1-(3'-(4-bromophenyl)-3'-hydroxy-2'-methyl-1'-oxo-4'-hexenyl)pyrrolidine(CAS DataBase Reference)
• NIST Chemistry Reference: (E,2'RS,3'RS)- and (E,2'RS,3'SR)-1-(3'-(4-bromophenyl)-3'-hydroxy-2'-methyl-1'-oxo-4'-hexenyl)pyrrolidine(97060-59-8)
• EPA Substance Registry System: (E,2'RS,3'RS)- and (E,2'RS,3'SR)-1-(3'-(4-bromophenyl)-3'-hydroxy-2'-methyl-1'-oxo-4'-hexenyl)pyrrolidine(97060-59-8)

Safety Data

• Hazardous Substances Data: 97060-59-8(Hazardous Substances Data)

Upstream product

• 99-90-1 para-bromoacetophenone 
• 122969-81-7 1-(4-bromophenyl)-3-hydroxybutan-1-one 
• 4553-05-3 1-pyrrolidin-1-yl-propan-1-one 
• 97060-28-1 (E)-1-(4-bromophenyl)-3-hydroxybutan-1-one 

Relevant articles and documents

Cerium(III) amide enolate. Addition of propionamide to conjugated enones

The cerium(III) enolate of propionamide 1 was found to undergo preferential 1,2-addition with most of the sterically hindered conjugated enones studied. The effects of HMPA and 12-crown-4 on the regioselectivity were also investigated.

Stereoselection in the Michael Addition Reaction. 2. Stereochemistry of the Kinetic Michael Reaction of Amide Enolates with Enones

An extensive study of structure-stereoselectivity relationships in the kinetic Michael addition of preformed lithium enolates to enones has uncovered some reactions of sufficiently high diastereoselectivity as to be synthetically attractive and has allowe