97850-68-5Relevant articles and documents
ON CARBONYL PARTICIPATION IN THE SOLVOLYSES OF α-KETO MESYLATES
Creary, Xavier,McDonald, Steven R.,Eggers, Mark D.
, p. 811 - 814 (2007/10/02)
α-amido mesylates generally solvolyze giving α-keto cations, bypassing cyclic ions derived from carbonyl (kΔ) participation.A possible exception is the N,N-dimethylamido mesylate derived from (S)-mandelic acid in trifluoroacetic acid which gives a small amount (9percent) of retained product.