98017-92-6

Basic information

• Product Name: 1,3-Propanediol, 2-phenyl-, diacetate
• Synonyms: 2-phenyl-1,3-propanediol diacetate;1.3-Diacetoxy-2-phenyl-propan;1,3-diacetoxy-2-phenylpropane;2-Phenyl-1,3-diacetoxy-propan;2-phenyl-1,3-diacetoxypropane;1,3-Propanediol,2-phenyl-,diacetate;1,3-PROPANEDIOL, 2-PHENYL-, DIACETATE
• CAS NO: 98017-92-6
• Molecular Formula: C13H16O4
• Molecular Weight: 236.268
• Mol File: 98017-92-6.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 1,3-Propanediol, 2-phenyl-, diacetate(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Propanediol, 2-phenyl-, diacetate(98017-92-6)
• EPA Substance Registry System: 1,3-Propanediol, 2-phenyl-, diacetate(98017-92-6)

Safety Data

• Hazardous Substances Data: 98017-92-6(Hazardous Substances Data)

Upstream product

• 1570-95-2 2-phenylpropane-1, 3-diol 
• 108-24-7 acetic anhydride 
• 108-05-4 vinyl acetate 
• 75-36-5 acetyl chloride 
• 506-96-7 Acetyl bromide 
• 62559-35-7 5-Phenyl-2,2,8,8-tetramethyl-3,7-dioxa-2,8-disilanonane 

Downstream Products

• 110230-69-8 (S)-1-acetoxy-3-hydroxy-2-phenylpropane 
• 91748-03-7 1,3-dihydroxy-2-(4-nitrophenyl)propane 
• 131682-39-8 Acetic acid (S)-3-hydroxy-2-(4-nitro-phenyl)-propyl ester 
• 131605-42-0 Acetic acid (R)-3-hydroxy-2-(4-nitro-phenyl)-propyl ester 
• 131605-42-0 Acetic acid 3-hydroxy-2-(4-nitro-phenyl)-propyl ester 
• 131605-45-3 (-)-3-acetoxy-2-(4-aminophenyl)propan-1-ol 
• 131605-45-3 Acetic acid 2-(4-amino-phenyl)-3-hydroxy-propyl ester 
• 131605-53-3 1-acetoxy-3-(4-nitrobenzyloxycarbonyloxy)-2-(4-nitrophenyl)propane 
• 131605-33-9 1,3-diacetoxy-2-<(4-benzyloxycarbonylamino)phenyl>propane 
• 131605-32-8 1,3-diacetoxy-2-(4-benzamidophenyl)propane 
• 131605-31-7 1,3-diacetoxy-2-(4-acetamidophenyl)propane 
• 131605-52-2 1-acetoxy-3-benzyloxycarbonyloxy-2-phenylpropane 
• 131605-46-4 Acetic acid 2-(4-acetylamino-phenyl)-3-hydroxy-propyl ester 
• 131605-30-6 1,3-diacetoxy-2-(4-aminophenyl)propane 

Relevant articles and documents

Selective mono-acylation of meso- and C2-symmetric 1,3- and 1,4-diols

The direct one-pot mono-acylation of meso and C2-symmetric 1,3- and 1,4-diols has been achieved using carboxylic acid anhydrides and catalytic amounts of cerium trichloride.

Lipase-based HPLC stationary phase: Enantioselective synthesis of 2- substituted 1,3-propanediol monoacetates

Pseudomonas cepacia lipase (PCL) has been immobilized by coating the enzyme on an epoxysilica HPLC column. The biocatalyst has been successfully used for the preparation of both the enantiomers of 3-acetoxy-2-benzyl- propan-1-ol and of 3-acetoxy-2-methylpropan-1-ol. The immobilized enzyme is active after months of use either in aqueous or in organic media. (C) 1999 Elsevier Science Ltd.

A Chemoenzymatic Synthesis of Both Enantiomers of 2-Phenyl-3-hydroxypropylcarbamate, a Metabolite of Felbamate

PPL catalyzed desymmetrization of 2-phenyl-1,3-propanediol (3) was the key step in the chemoenzymatic synthesis of both enantiomers of 2-phenyl-3-hydroxypropylcarbamate (2).Unsuccessful attempts at enzyme catalyzed (PPL, Novo SP435) transcarbamoylation, aminolysis and ammonolysis are also described.