98716-00-8

Basic information

• Product Name: hydroxo(meso-tetrakis(2,6-difluorophenyl)porphirinato)iron(III)
• Synonyms: hydroxo(meso-tetrakis(2,6-difluorophenyl)porphirinato)iron(III)
• CAS NO: 98716-00-8
• Molecular Weight: 829.511
• Mol File: 98716-00-8.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: hydroxo(meso-tetrakis(2,6-difluorophenyl)porphirinato)iron(III)(CAS DataBase Reference)
• NIST Chemistry Reference: hydroxo(meso-tetrakis(2,6-difluorophenyl)porphirinato)iron(III)(98716-00-8)
• EPA Substance Registry System: hydroxo(meso-tetrakis(2,6-difluorophenyl)porphirinato)iron(III)(98716-00-8)

Safety Data

• Hazardous Substances Data: 98716-00-8(Hazardous Substances Data)

Upstream product

• 80937-33-3 oxygen 
• 99038-25-2 [meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porhpyrinato]-iron(III) chloride 
• 1206795-61-0 C₄₄H₂₀F₈FeN₄⁽¹⁺⁾*F₆Sb^(1-) 
• 7732-18-5 water 
• 379217-58-0 superoxo(tetrakis(2,6-difluorophenyl)porphyrinato)(tetrahydrofuran)iron(III) 
• 92-83-1 xanthene 
• 4217-54-3 9,10-dihydro-10-methylacridine 
• 162257-76-3 tetrakis(2,6-difluorophenyl)porphyrinate^(2-)iron(II) 
• 96-76-4 2,4-di-tert-Butylphenol 

Downstream Products

• 162257-76-3 tetrakis(2,6-difluorophenyl)porphyrinate^(2-)iron(II) 
• 180151-16-0 perchloratoiron(III) tetrakis(2,6-difluorophenylporphyrin) 

Relevant articles and documents

A selective stepwise heme oxygenase model system: An iron(IV)-oxo porphyrin π-cation radical leads to a verdoheme-type compound via an isoporphyrin intermediate

The selective oxidation of the α-position of two heme-Fe III tetraarylporphryinate complexes occurs when water(hydroxide) attacks their oxidized Cmpd I-type equivalents, high-valent FeIV=O π-cation radical species ((P+?)FeIV=O). Stepwise intermediate formation occurs, as detected by UV-vis spectroscopic monitoring or mass spectrometric interrogation, being iron(III) isoporphyrins, iron(III) benzoyl-biliverdins, and the final verdoheme-like products. Heme oxygenase (HO) enzymes could proceed through heterolytic cleavage of an iron(III)-hydroperoxo intermediate to form a transient Cmpd I-type species.

Hydrogen atom abstraction and hydride transfer reactions by iron(IV)-oxo porphyrins

(Chemical Equation Presented) True identity revealed: The C-H bond activation of alkyl aromatics by synthetic iron(IV)-oxo porphyrin species and the hydride transfer of NADH analogues to them occur through H-atom abstraction and proton-coupled electron-transfer mechanisms, respectively. Mechanistic studies revealed that iron(IV)-oxo porphyrin π, not iron(IV)-oxo porphyrin pradical cations, are the true oxidant.

Copper-Dioxygen Reactivity Involved in the Formation of μ-oxoIII-O-CuIIL>+ Heterodinuclear Complexes (por = porphyrinate, L = tetradentate ligand), and Novel Synthesis of Square-Planar FeII(por) Species

In the reaction of FeII(por) species with I(MeCN)>+ and O2 to give μ-oxoIII-O-CuIIL>+ 3 (por = porphyrinate, L = tetradentate ligand), copper-dioxygen adducts or their decomposition products must be present, otherwise III-OH> or III-O-FeIII(por)> products appear; a novel synthesis of square-planar FeII(por) is also described.