99387-18-5

Basic information

• Product Name: (4-Hexyloxy-phenyl)-(6-propoxy-pyridin-3-yl)-diazene
• Synonyms: (4-Hexyloxy-phenyl)-(6-propoxy-pyridin-3-yl)-diazene
• CAS NO: 99387-18-5
• Molecular Weight: 341.453
• Mol File: 99387-18-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4-Hexyloxy-phenyl)-(6-propoxy-pyridin-3-yl)-diazene(CAS DataBase Reference)
• NIST Chemistry Reference: (4-Hexyloxy-phenyl)-(6-propoxy-pyridin-3-yl)-diazene(99387-18-5)
• EPA Substance Registry System: (4-Hexyloxy-phenyl)-(6-propoxy-pyridin-3-yl)-diazene(99387-18-5)

Safety Data

• Hazardous Substances Data: 99387-18-5(Hazardous Substances Data)

Upstream product

• 99387-23-2 5-nitro-2-propoxypyridine 
• 52025-35-1 6-propoxypyridin-3-amine 
• 4548-45-2 2-chloro-5-nitropyridine 
• 638-45-9 1-Iodohexane 

Relevant articles and documents

Liquid Crystalline Compounds Bearing Pyridine Ring: 3-(4-Alkoxyphenylazoxy)-6-alkoxypyridines

3-(4-Alkoxyphenylazo)-6-alkoxypyridines (6) with n-alkoxyl (C1-C6) groups were synthesized by the coupling reaction of phenol with 6-alkoxy-3-pyridine diazonium chloride prepared from 2-chloro-5-nitropyridine via 2-alkoxy-5-nitro and 2-alkoxy-5-aminopyridines and subsequent etherification with n-alkyl iodides.Mild oxidation of 6 with hydrogen peroxide in acetic acid provided 3-6-alkoxy-pyridines (7) containing nearly equimolar amounts of ONN (8) and NNO (8') isomers.Centrifugal liquid chromatography satisfactorily separated these two isomers.Mesomorphic behaviors of 8 and 8' are characteristic in that the pyridine ring exerts polar effects and 8 are more balanced in polarity than 8'.Compounds 7 possess rather lower mesomorphic ranges than 8 and 8'.Some of compounds 6 indicate mesomorphic ranges but generally azo compounds are inferior to azoxy ones.